Übergangsmetall-methylen-komplexe. VIII. Massenspektrometrische untersuchungen an μ-methylen-komplexen von kobalt, rhodium, mangan und eisen

Klaus K. Mayer; Wolfgang A. Herrmann

doi:10.1016/S0022-328X(00)84819-6

Übergangsmetall-methylen-komplexe. VIII. Massenspektrometrische untersuchungen an μ-methylen-komplexen von kobalt, rhodium, mangan und eisen

Klaus K. Mayer
, Wolfgang A. Herrmann

University of Regensburg

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The electron impact induced decomposition pathways of several μ-methylene complexes of Co, Rh, Mn, and Fe were elucidated by high resolution measurements, analysis of metastable transitions, and ²H-labelling. The fragmentation patterns are discussed with regard to the nature of the different central atoms and methylene ligands, and compared With those of terminal carbene complexes.

Original language	German
Pages (from-to)	361-374
Number of pages	14
Journal	Journal of Organometallic Chemistry
Volume	182
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)84819-6
State	Published - 11 Dec 1979
Externally published	Yes

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title = "{\"U}bergangsmetall-methylen-komplexe. VIII. Massenspektrometrische untersuchungen an μ-methylen-komplexen von kobalt, rhodium, mangan und eisen",

abstract = "The electron impact induced decomposition pathways of several μ-methylene complexes of Co, Rh, Mn, and Fe were elucidated by high resolution measurements, analysis of metastable transitions, and 2H-labelling. The fragmentation patterns are discussed with regard to the nature of the different central atoms and methylene ligands, and compared With those of terminal carbene complexes.",

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AU - Herrmann, Wolfgang A.

PY - 1979/12/11

Y1 - 1979/12/11

N2 - The electron impact induced decomposition pathways of several μ-methylene complexes of Co, Rh, Mn, and Fe were elucidated by high resolution measurements, analysis of metastable transitions, and 2H-labelling. The fragmentation patterns are discussed with regard to the nature of the different central atoms and methylene ligands, and compared With those of terminal carbene complexes.

AB - The electron impact induced decomposition pathways of several μ-methylene complexes of Co, Rh, Mn, and Fe were elucidated by high resolution measurements, analysis of metastable transitions, and 2H-labelling. The fragmentation patterns are discussed with regard to the nature of the different central atoms and methylene ligands, and compared With those of terminal carbene complexes.

UR - https://www.scopus.com/pages/publications/0039319366

U2 - 10.1016/S0022-328X(00)84819-6

DO - 10.1016/S0022-328X(00)84819-6

M3 - Artikel

AN - SCOPUS:0039319366

SN - 0022-328X

VL - 182

SP - 361

EP - 374

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Übergangsmetall-methylen-komplexe. VIII. Massenspektrometrische untersuchungen an μ-methylen-komplexen von kobalt, rhodium, mangan und eisen

Abstract

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