TY - JOUR
T1 - Übergangsmetall-methylen-komplexe. VIII. Massenspektrometrische untersuchungen an μ-methylen-komplexen von kobalt, rhodium, mangan und eisen
AU - Mayer, Klaus K.
AU - Herrmann, Wolfgang A.
PY - 1979/12/11
Y1 - 1979/12/11
N2 - The electron impact induced decomposition pathways of several μ-methylene complexes of Co, Rh, Mn, and Fe were elucidated by high resolution measurements, analysis of metastable transitions, and 2H-labelling. The fragmentation patterns are discussed with regard to the nature of the different central atoms and methylene ligands, and compared With those of terminal carbene complexes.
AB - The electron impact induced decomposition pathways of several μ-methylene complexes of Co, Rh, Mn, and Fe were elucidated by high resolution measurements, analysis of metastable transitions, and 2H-labelling. The fragmentation patterns are discussed with regard to the nature of the different central atoms and methylene ligands, and compared With those of terminal carbene complexes.
UR - http://www.scopus.com/inward/record.url?scp=0039319366&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)84819-6
DO - 10.1016/S0022-328X(00)84819-6
M3 - Artikel
AN - SCOPUS:0039319366
SN - 0022-328X
VL - 182
SP - 361
EP - 374
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 3
ER -