Übergangsmetall-methylen-komplexe. IX. Molekülstruktur von μ-methylen-bis[dicarbonyl(η5-methylcyclopentadienyl)mangan](MnMn), μCH2[(η5-CH3C5H4)Mn(CO)2]2

Michael Creswick; Ivan Bernal; Wolfgang A. Herrmann

doi:10.1016/S0022-328X(00)92372-6

Übergangsmetall-methylen-komplexe. IX. Molekülstruktur von μ-methylen-bis[dicarbonyl(η⁵-methylcyclopentadienyl)mangan](MnMn), μCH₂[(η⁵-CH₃C₅H₄)Mn(CO)₂]₂

Michael Creswick, Ivan Bernal, Wolfgang A. Herrmann

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

The structure of μ-methylenebis[dicarbonyl(η⁵-methylcyclopentadienyl)-manganese](MnMn) has been established by means of X-ray diffraction techniques to consist of two (η⁵-C₅H₄CH₃)Mn(CO)₂ fragments which are linked by a bridging CH₂ ligand and a metal to metal bond. Dimetallacyclopropanes of this type can easily be distinguished from the related Fischer-type carbenes as well as from μ-alkylidene complexes without metalmetal bonds by ¹³C NMR spectroscopy.

Original language	German
Pages (from-to)	C39-C42
Journal	Journal of Organometallic Chemistry
Volume	172
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)92372-6
State	Published - 19 Jun 1979
Externally published	Yes

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Cite this

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title = "{\"U}bergangsmetall-methylen-komplexe. IX. Molek{\"u}lstruktur von μ-methylen-bis[dicarbonyl(η5-methylcyclopentadienyl)mangan](MnMn), μCH2[(η5-CH3C5H4)Mn(CO)2]2",

abstract = "The structure of μ-methylenebis[dicarbonyl(η5-methylcyclopentadienyl)-manganese](MnMn) has been established by means of X-ray diffraction techniques to consist of two (η5-C5H4CH3)Mn(CO)2 fragments which are linked by a bridging CH2 ligand and a metal to metal bond. Dimetallacyclopropanes of this type can easily be distinguished from the related Fischer-type carbenes as well as from μ-alkylidene complexes without metalmetal bonds by 13C NMR spectroscopy.",

author = "Michael Creswick and Ivan Bernal and Herrmann, \{Wolfgang A.\}",

year = "1979",

month = jun,

day = "19",

doi = "10.1016/S0022-328X(00)92372-6",

language = "Deutsch",

volume = "172",

pages = "C39--C42",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

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T1 - Übergangsmetall-methylen-komplexe. IX. Molekülstruktur von μ-methylen-bis[dicarbonyl(η5-methylcyclopentadienyl)mangan](MnMn), μCH2[(η5-CH3C5H4)Mn(CO)2]2

AU - Creswick, Michael

AU - Bernal, Ivan

AU - Herrmann, Wolfgang A.

PY - 1979/6/19

Y1 - 1979/6/19

N2 - The structure of μ-methylenebis[dicarbonyl(η5-methylcyclopentadienyl)-manganese](MnMn) has been established by means of X-ray diffraction techniques to consist of two (η5-C5H4CH3)Mn(CO)2 fragments which are linked by a bridging CH2 ligand and a metal to metal bond. Dimetallacyclopropanes of this type can easily be distinguished from the related Fischer-type carbenes as well as from μ-alkylidene complexes without metalmetal bonds by 13C NMR spectroscopy.

AB - The structure of μ-methylenebis[dicarbonyl(η5-methylcyclopentadienyl)-manganese](MnMn) has been established by means of X-ray diffraction techniques to consist of two (η5-C5H4CH3)Mn(CO)2 fragments which are linked by a bridging CH2 ligand and a metal to metal bond. Dimetallacyclopropanes of this type can easily be distinguished from the related Fischer-type carbenes as well as from μ-alkylidene complexes without metalmetal bonds by 13C NMR spectroscopy.

UR - https://www.scopus.com/pages/publications/4243905408

U2 - 10.1016/S0022-328X(00)92372-6

DO - 10.1016/S0022-328X(00)92372-6

M3 - Artikel

AN - SCOPUS:4243905408

SN - 0022-328X

VL - 172

SP - C39-C42

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Übergangsmetall-methylen-komplexe. IX. Molekülstruktur von μ-methylen-bis[dicarbonyl(η5-methylcyclopentadienyl)mangan](MnMn), μCH2[(η5-CH3C5H4)Mn(CO)2]2

Abstract

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Übergangsmetall-methylen-komplexe. IX. Molekülstruktur von μ-methylen-bis[dicarbonyl(η⁵-methylcyclopentadienyl)mangan](MnMn), μCH₂[(η⁵-CH₃C₅H₄)Mn(CO)₂]₂