TY - JOUR
T1 - Übergangsmetall-methylen-komplexe. IX. Molekülstruktur von μ-methylen-bis[dicarbonyl(η5-methylcyclopentadienyl)mangan](MnMn), μCH2[(η5-CH3C5H4)Mn(CO)2]2
AU - Creswick, Michael
AU - Bernal, Ivan
AU - Herrmann, Wolfgang A.
PY - 1979/6/19
Y1 - 1979/6/19
N2 - The structure of μ-methylenebis[dicarbonyl(η5-methylcyclopentadienyl)-manganese](MnMn) has been established by means of X-ray diffraction techniques to consist of two (η5-C5H4CH3)Mn(CO)2 fragments which are linked by a bridging CH2 ligand and a metal to metal bond. Dimetallacyclopropanes of this type can easily be distinguished from the related Fischer-type carbenes as well as from μ-alkylidene complexes without metalmetal bonds by 13C NMR spectroscopy.
AB - The structure of μ-methylenebis[dicarbonyl(η5-methylcyclopentadienyl)-manganese](MnMn) has been established by means of X-ray diffraction techniques to consist of two (η5-C5H4CH3)Mn(CO)2 fragments which are linked by a bridging CH2 ligand and a metal to metal bond. Dimetallacyclopropanes of this type can easily be distinguished from the related Fischer-type carbenes as well as from μ-alkylidene complexes without metalmetal bonds by 13C NMR spectroscopy.
UR - http://www.scopus.com/inward/record.url?scp=4243905408&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)92372-6
DO - 10.1016/S0022-328X(00)92372-6
M3 - Artikel
AN - SCOPUS:4243905408
SN - 0022-328X
VL - 172
SP - C39-C42
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 3
ER -