Chair of Inorganic Chemistry with Focus on New Materials

2024

An efficient multi-gram access in a two-step synthesis to soluble, nine-atomic, silylated silicon clusters

Frankiewicz, K. M., Willeit, N. S., Hlukhyy, V. & Fässler, T. F., Dec 2024, In: Nature Communications. 15, 1, 10715.

Research output: Contribution to journal › Article › peer-review

Open Access

Dendritic Copper Current Collectors as a Capacity Boosting Material for Polymer-Templated Si/Ge/C Anodes in Li-Ion Batteries

Weindl, C. L., Fajman, C. E., Xu, Z., Zheng, T., Möhl, G. E., Chaulagain, N., Shankar, K., Gilles, R., Fässler, T. F. & Müller-Buschbaum, P., 17 Jan 2024, In: ACS Applied Materials and Interfaces. 16, 2, p. 2309-2318 10 p.

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Direct Band Gap Semiconductors with Two- and Three-Dimensional Triel-Phosphide Frameworks (Triel=Al, Ga, In)

Restle, T. M. F., Zeitz, S., Stanley, P. M., Karttunen, A. J., Meyer, J., Raudaschl-Sieber, G., Klein, W. & Fässler, T. F., 25 Mar 2024, In: Chemistry - A European Journal. 30, 18, e202304097.

Research output: Contribution to journal › Article › peer-review

Open Access

1 Scopus citations

Electronic Structure Analysis of the A₁₀Tt₂P₆ System (A=Li−Cs; Tt=Si, Ge, Sn) and Synthesis of the Direct Band Gap Semiconductor K₁₀Sn₂P₆

Zeitz, S., Antoniuk, H., Hlukhyy, V. & Fässler, T. F., 16 Apr 2024, In: Chemistry - A European Journal. 30, 22, e202400002.

Research output: Contribution to journal › Article › peer-review

Open Access

1 Scopus citations

Functionalised [Ge₉Ni] Clusters as Homogeneous Single-Site Catalysts for Olefin Isomerisation Reactions

Willeit, N. S., Klein, W., Coburger, P., Fritz-Langhals, E. & Fässler, T. F., 22 Jan 2024, In: ChemCatChem. 16, 2, e202301200.

Research output: Contribution to journal › Article › peer-review

Open Access

9 Scopus citations

Large Number of Direct or Pseudo-Direct Band Gap Semiconductors among A₃TrPn₂ Compounds with A = Li, Na, K, Rb, Cs; Tr = Al, Ga, In; Pn = P, As

Zeitz, S., Kuznetsova, Y. & Fässler, T. F., Sep 2024, In: Molecules. 29, 17, 4087.

Research output: Contribution to journal › Article › peer-review

Open Access

Na₃Ge₂P₃: A Zintl Phase Featuring [P₃Ge-GeP₃] Dimers as Building Blocks

Botta, M., Zeitz, S., Klein, W., Raudaschl-Sieber, G. & Fässler, T. F., 2024, (Accepted/In press) In: Inorganic Chemistry.

Research output: Contribution to journal › Article › peer-review

Open Access

Open Sn Framework Structure Hosting Bi Guest atoms–Synthesis, Crystal and Electronic Structure of Na₁₃Sn₂₆Bi

Zeitz, S., Boyko, M., Ponou, S., Hlukhyy, V. & Fässler, T. F., 2024, (Accepted/In press) In: Chemistry - A European Journal.

Research output: Contribution to journal › Article › peer-review

Open Access

Synthesis, Crystal structure, electronic structure, and Raman spectra of Li₄Sr₂SiP₄

Daiber, V., Zeitz, S., Hlukhyy, V., Dankert, D. & Fässler, T. F., 16 Feb 2024, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 650, 4, e202300244.

Research output: Contribution to journal › Article › peer-review

Open Access

1 Scopus citations

Synthesis, Structure and Catalytic Properties of Hyp₃[Ge₉Rh]PPh₃

Willeit, N. S., Hlukhyy, V. & Fässler, T. F., 16 Dec 2024, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 650, 24, e202400171.

Research output: Contribution to journal › Article › peer-review

Open Access

2023

Crystal structure of undecacalcium decaarsenide, Ca₁₁As₁₀

Hoffmann, A. V., Hlukhyy, V. & Fassler, T. F., 1 Jan 2023, In: Zeitschrift fur Kristallographie - New Crystal Structures. 238, 1, p. 1-3 3 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Scopus citations

K₇In₄As₆ and K₃InAs₂ - Two more Zintl phases showing the rich variety of In-As polyanion structures

Boyko, M., Hlukhyy, V. & Fässler, T. F., 2 Nov 2023, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 649, 21, e202300164.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Scopus citations

Lithium-ion Mobility in Li₆B₁₈(Li₃N) and Li Vacancy Tuning in the Solid Solution Li₆B₁₈(Li₃N)_1−x(Li₂O)_x

Restle, T. M. F., Scherf, L., Dums, J. V., Mutschke, A. G., Spranger, R. J., Kirchhain, H., Karttunen, A. J., van Wüllen, L. & Fässler, T. F., 1 Mar 2023, In: Angewandte Chemie International Edition in English. 62, 10, e202213962.

Research output: Contribution to journal › Article › peer-review

Open Access

4 Scopus citations

Mechanism of Li-Ion Migration in the Superionic Conducting Open-Framework Structure Li₆B₁₈(Li₃N)_1-x(Li₂O)_x (0 ≤ x ≤ 1)

Spranger, R. J., Kirchhain, H., Restle, T. M. F., Dums, J. V., Karttunen, A. J., van Wüllen, L. & Fässler, T. F., 26 Jan 2023, In: Journal of Physical Chemistry C. 127, 3, p. 1622-1632 11 p.

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Probing Charge-Transfer Processes in a Covalently Linked [Ge₉]-Cluster Imine Dyad

Wallach, C., Selic, Y., Geitner, F. S., Kumar, A., Thyrhaug, E., Hauer, J., Karttunen, A. J. & Fässler, T. F., 17 Jul 2023, In: Angewandte Chemie International Edition in English. 62, 29, e202304088.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Scopus citations

Structural characteristics of mixed nido-[Si_9−xGe_x]⁴⁻ (x=1, 2) Zintl clusters in solution and within solvent crystals

Jantke, L. A., Karttunen, A. J. & Fässler, T. F., 1 Feb 2023, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 649, 3, e202200276.

Research output: Contribution to journal › Article › peer-review

Open Access

1 Scopus citations

Synthesis, Structure and Physical Properties of the Sodium-Rich Phosphidogermanate Na₈GeP₄

Botta, M., Zeitz, S. & Fässler, T. F., 16 Oct 2023, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 649, 20, e202300166.

Research output: Contribution to journal › Article › peer-review

Open Access

1 Scopus citations

Toluene-Mediated Morphology Tuning of Diblock Copolymer-Templated Porous Si/Ge/K/C Thin Films for Li-Ion Batteries

Weindl, C. L., Wu, K., Fajman, C. E., Xu, Z., Zheng, T., Tian, T., Harder, C., Sochor, B., Roth, S. V., Fässler, T. F. & Müller-Buschbaum, P., Oct 2023, In: Advanced Energy and Sustainability Research. 4, 10, 2300096.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Scopus citations

2022

Ca₁₄FeAs₁₁ – A structure comprising structural motifs of iron-based superconductors and Ca-As Zintl phases

Hoffmann, A. V., Fässler, T. F. & Hlukhyy, V., 13 Dec 2022, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 648, 23, e202200168.

Research output: Contribution to journal › Article › peer-review

Open Access

1 Scopus citations

Chemi-Inspired Silicon Allotropes—Experimentally Accessible Si₉ Cages as Proposed Building Block for 1D Polymers, 2D Sheets, Single-Walled Nanotubes, and Nanoparticles

Jantke, L. A., Karttunen, A. J. & Fässler, T. F., 1 Feb 2022, In: Molecules. 27, 3, 822.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Scopus citations

Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ ⁶O₆)potassium(2-methylphenylamino)ethyl-2-methylphenylamide ammoniate (1/3.5), [K(18-crown-6)](o-CH₃C₆H₄)NH(CH₂)₂N(o-CH₃C₆H₄) 3.5 NH₃, C₂₈H_53.5KN_5.5O₆

Wallach, C., Klein, W. & Fässler, T. F., 1 Oct 2022, In: Zeitschrift fur Kristallographie - New Crystal Structures. 237, 5, p. 897-901 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Crystal structure of N ²,N ⁴-dimesitylpentane-2,4-diamine, C₂₃H₃₄N₂

Wallach, C., Klein, W. & Fässler, T. F., 1 Oct 2022, In: Zeitschrift fur Kristallographie - New Crystal Structures. 237, 5, p. 893-895 3 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Effect of Solvent Vapor Annealing on Diblock Copolymer-Templated Mesoporous Si/Ge/C Thin Films: Implications for Li-Ion Batteries

Weindl, C. L., Fajman, C. E., Giebel, M. A., Wienhold, K. S., Yin, S., Tian, T., Geiger, C., Kreuzer, L. P., Schwartzkopf, M., Roth, S. V., Fässler, T. F. & Müller-Buschbaum, P., 27 May 2022, In: ACS Applied Nano Materials. 5, 5, p. 7278-7287 10 p.

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Inverse Opal-Structured Sn and Sn/Ge Films from Soluble Zintl Clusters as Precursors

Geier, S., Kratky, T., Günther, S. & Fässler, T. F., 12 Aug 2022, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 648, 15, e202100362.

Research output: Contribution to journal › Article › peer-review

Open Access

1 Scopus citations

Li₅SnP₃ – a Member of the Series Li_10+4xSn_2−xP₆ for x=0 Comprising the Fast Lithium-Ion Conductors Li₈SnP₄ (x=0.5) and Li₁₄SnP₆ (x=1)

Strangmüller, S., Müller, D., Raudaschl-Sieber, G., Kirchhain, H., van Wüllen, L. & Fässler, T. F., 21 Feb 2022, In: Chemistry - A European Journal. 28, 10, e202104219.

Research output: Contribution to journal › Article › peer-review

Open Access

1 Scopus citations

Nonagermanide Zintl Clusters with Mg²⁺ Counter Ions

Wallach, C., Klein, W. & Fässler, T. F., 14 Oct 2022, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 648, 19, e202200065.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Scopus citations

Oxidative coupling of silylated nonagermanide clusters

Wallach, C., Klein, W. & Fässler, T. F., 4 Apr 2022, In: Chemical Communications. 58, 36, p. 5486-5489 4 p.

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Planar Si₅ and Ge₅ Pentagons beside Isolated Phosphide Anions in Lithium Phosphide Tetrelides Li_10+xSi₅P and Li_10+xGe₅P

Eickhoff, H., Klein, W., Toffoletti, L., Raudaschl-Sieber, G. & Fässler, T. F., 25 May 2022, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 648, 10, e202100376.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Scopus citations

Super-Ionic Conductivity in ω-Li₉TrP₄ (Tr = Al, Ga, In) and Lithium Diffusion Pathways in Li₉AlP₄ Polymorphs

Restle, T. M. F., Strangmüller, S., Baran, V., Senyshyn, A., Kirchhain, H., Klein, W., Merk, S., Müller, D., Kutsch, T., van Wüllen, L. & Fässler, T. F., 10 Nov 2022, In: Advanced Functional Materials. 32, 46, 2112377.

Research output: Contribution to journal › Article › peer-review

Open Access

8 Scopus citations

2021

Aliovalent substitution in phosphide-based materials – Crystal structures of Na₁₀AlTaP₆ and Na₃GaP₂ featuring edge-sharing EP₄ tetrahedra (E=Al/Ta and Ga)

Restle, T. M. F., Zeitz, S., Meyer, J., Klein, W., Raudaschl-Sieber, G., Karttunen, A. J. & Fässler, T. F., 27 Sep 2021, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 647, 18, p. 1804-1814 11 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Scopus citations

Boranyl-Functionalized [Ge₉] Clusters: Providing the Idea of Intramolecular Ge/B Frustrated Lewis Pairs

Wallach, C., Geitner, F. S., Karttunen, A. J. & Fässler, T. F., 1 Feb 2021, In: Angewandte Chemie International Edition in English. 60, 5, p. 2648-2653 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

25 Scopus citations

Crystal structure of (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane-κ ⁸N ₂, O ₆) potassium cyclopentadienide, [K([2.2.2]crypt)]Cp, C₂₃H₄₁KN₂O₆

Fischer, C., Klein, W. & Fässler, T. F., 1 Dec 2021, In: Zeitschrift fur Kristallographie - New Crystal Structures. 236, 6, p. 1259-1261 3 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Evolving Highly Active Oxidic Iron(III) Phase from Corrosion of Intermetallic Iron Silicide to Master Efficient Electrocatalytic Water Oxidation and Selective Oxygenation of 5-Hydroxymethylfurfural

Hausmann, J. N., Beltrán-Suito, R., Mebs, S., Hlukhyy, V., Fässler, T. F., Dau, H., Driess, M. & Menezes, P. W., 8 Jul 2021, In: Advanced Materials. 33, 27, 2008823.

Research output: Contribution to journal › Article › peer-review

Open Access

104 Scopus citations

Fast Lithium-Ion Conduction in Phosphide Li₉GaP₄

Restle, T. M. F., Sedlmeier, C., Kirchhain, H., Klein, W., Raudaschl-Sieber, G., Van Wüllen, L. & Fässler, T. F., 27 Apr 2021, In: Chemistry of Materials. 33, 8, p. 2957-2966 10 p.

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Filled trivacant icosahedra as building fragments in 17-atom endohedral germanides [TM₂@Ge₁₇]ⁿ⁻(TM= Co, Ni)

Wallach, C., Selic, Y., Witzel, B. J. L., Klein, W. & Fässler, T. F., 21 Oct 2021, In: Dalton Transactions. 50, 39, p. 13671-13675 5 p.

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

FLP-type nitrile activation and cyclic ether ring-opening by halo-borane nonagermanide-cluster Lewis acid-base pairs

Wallach, C., Geitner, F. S. & Fässler, T. F., 28 May 2021, In: Chemical Science. 12, 20, p. 6969-6976 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

20 Scopus citations

Investigations on the Solubility of Sn₄-Cluster Compounds in Liquid Ammonia

Klein, W., Benda, C. B., Henneberger, T., Witzel, B. J. L. & Fässler, T. F., 25 Nov 2021, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 647, 22, p. 2047-2054 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Scopus citations

Molecules Meet Solids: From Wade–Mingos Clusters to Intermetalloid Clusters

Klein, W., Schier, A. & Fässler, T. F., 2021, In: Structure and Bonding. 188, p. 149-196 48 p.

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

On the Crystal Structure and Conductivity of Na₃P

Eickhoff, H., Dietrich, C., Klein, W., Zeier, W. G. & Fässler, T. F., 11 Feb 2021, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 647, 2-3, p. 28-33 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

13 Scopus citations

On the Oxidation of [Ge₉]⁴⁻ – Crystal Structures and Raman Spectroscopic Investigation of Linked Ge₉ Clusters

Mayer, K., Klein, W., Geier, S. & Fässler, T. F., 24 Feb 2021, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 647, 4, p. 377-384 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

5 Scopus citations

Supertetrahedral polyanionic network in the first lithium phosphidoindate Li₃InP₂- structural similarity to Li₂SiP₂and Li₂GeP₂and dissimilarity to Li₃AlP₂and Li₃GaP₂

Restle, T. M. F., Deringer, V. L., Meyer, J., Raudaschl-Sieber, G. & Fässler, T. F., 28 Jan 2021, In: Chemical Science. 12, 4, p. 1278-1285 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

10 Scopus citations

Surface-Anisotropic Janus Silicon Quantum Dots via Masking on 2D Silicon Nanosheets

Kloberg, M. J., Yu, H., Groß, E., Eckmann, F., Restle, T. M. F., Fässler, T. F., Veinot, J. G. C. & Rieger, B., 23 Sep 2021, In: Advanced Materials. 33, 38, 2100288.

Research output: Contribution to journal › Article › peer-review

Open Access

12 Scopus citations

Synthesis, structure and diffusion pathways of fast lithium-ion conductors in the polymorphs α- And β-Li₈SnP₄

Strangmüller, S., Eickhoff, H., Klein, W., Raudaschl-Sieber, G., Kirchhain, H., Kutsch, T., Baran, V., Senyshyn, A., van Wüllen, L., Gasteiger, H. A. & Fässler, T. F., 21 Jul 2021, In: Journal of Materials Chemistry A. 9, 27, p. 15254-15268 15 p.

Research output: Contribution to journal › Article › peer-review

Open Access

12 Scopus citations

2020

Cluster Expansion versus Complex Formation: Coinage Metal Coordination to Silylated [Ge₉] Cages

Geitner, F. S. & Fässler, T. F., 19 Oct 2020, In: Inorganic Chemistry. 59, 20, p. 15218-15227 10 p.

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Contrasting Structure and Bonding of a Copper-Rich and a Zinc-Rich Intermetalloid Cu/Zn Cluster

Schütz, M., Muhr, M., Freitag, K., Gemel, C., Kahlal, S., Saillard, J. Y., Da Silva, A. C. H., Da Silva, J. L. F., Fässler, T. F. & Fischer, R. A., 6 Jul 2020, In: Inorganic Chemistry. 59, 13, p. 9077-9085 9 p.

Research output: Contribution to journal › Article › peer-review

Open Access

9 Scopus citations

Crystal structure and spectroscopic analysis of the compatible solute nγ-acetyl-l-2,4-diaminobutyric acid

Martin, L., Klein, W., Schwaminger, S. P., Fässler, T. F. & Berensmeier, S., Dec 2020, In: Crystals. 10, 12, p. 1-11 11 p., 1136.

Research output: Contribution to journal › Article › peer-review

Open Access

1 Scopus citations

Extracting [Pd@Sn₉]^4– and [Rh@Pb₉]^4– Clusters from their Binary Alloys Using “Metal Scissors”

Boyko, M., Hlukhyy, V., Jin, H., Dums, J. & Fässler, T. F., 30 Sep 2020, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 646, 18, p. 1575-1582 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

8 Scopus citations

Fast Lithium Ion Conduction in Lithium Phosphidoaluminates

Restle, T. M. F., Sedlmeier, C., Kirchhain, H., Klein, W., Raudaschl-Sieber, G., Deringer, V. L., van Wüllen, L., Gasteiger, H. A. & Fässler, T. F., 27 Mar 2020, In: Angewandte Chemie International Edition in English. 59, 14, p. 5665-5674 10 p.

Research output: Contribution to journal › Article › peer-review

Open Access

31 Scopus citations

Intermediates and products of the reaction of Zn(ii) organyls with tetrel elementZintlions: Cluster extensionversuscomplexation

Wallach, C., Mayer, K., Henneberger, T., Klein, W. & Fässler, T. F., 21 May 2020, In: Dalton Transactions. 49, 19, p. 6191-6198 8 p.

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

K₁₀Ga₃Bi_6.65 – The First Compound in the Ternary A-Ga-Bi System Comprising Cyclic Tris-meta Borate-Analogous [Ga₃Bi₆]^9– Units and Bi₂ Dumbbells

Boyko, M., Hlukhyy, V. & Fässler, T. F., 15 Jul 2020, In: Zeitschrift fur Anorganische und Allgemeine Chemie. 646, 13, p. 659-664 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

5 Scopus citations

Chair of Inorganic Chemistry with Focus on New Materials

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