Vibronic coupling in the pE″ Rydberg series of NH3

A. Staib; W. Domcke

doi:10.1016/0009-2614(93)89194-M

Vibronic coupling in the pE″ Rydberg series of NH₃

A. Staib
, W. Domcke

TUM Emeriti of Excellence

Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

5 Zitate (Scopus)

Abstract

The Jahn-Teller effect in the pE″ Rydberg series on NH₃ is investigated within a simple multi-channel-quantum-defect-type model. The parameters of the model are determined from recently observed infrared-optical double resonance spectra of the B̃¹E″ (3p_x,y band system. Jahn-Teller induced vibrational autoionization effects and pronounced perturbations of high Rydberg members are analyzed. a.

Originalsprache	Englisch
Seiten (von - bis)	505-510
Seitenumfang	6
Fachzeitschrift	Chemical Physics Letters
Jahrgang	204
Ausgabenummer	5-6
DOIs	https://doi.org/10.1016/0009-2614(93)89194-M
Publikationsstatus	Veröffentlicht - 26 März 1993

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10.1016/0009-2614(93)89194-M

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title = "Vibronic coupling in the pE″ Rydberg series of NH3",

abstract = "The Jahn-Teller effect in the pE″ Rydberg series on NH3 is investigated within a simple multi-channel-quantum-defect-type model. The parameters of the model are determined from recently observed infrared-optical double resonance spectra of the {\~B}1E″ (3px,y band system. Jahn-Teller induced vibrational autoionization effects and pronounced perturbations of high Rydberg members are analyzed. a.",

author = "A. Staib and W. Domcke",

note = "Funding Information: This work has been supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie.",

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AU - Domcke, W.

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Y1 - 1993/3/26

N2 - The Jahn-Teller effect in the pE″ Rydberg series on NH3 is investigated within a simple multi-channel-quantum-defect-type model. The parameters of the model are determined from recently observed infrared-optical double resonance spectra of the B̃1E″ (3px,y band system. Jahn-Teller induced vibrational autoionization effects and pronounced perturbations of high Rydberg members are analyzed. a.

AB - The Jahn-Teller effect in the pE″ Rydberg series on NH3 is investigated within a simple multi-channel-quantum-defect-type model. The parameters of the model are determined from recently observed infrared-optical double resonance spectra of the B̃1E″ (3px,y band system. Jahn-Teller induced vibrational autoionization effects and pronounced perturbations of high Rydberg members are analyzed. a.

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