Thermodynamics of halogen bonded monolayer self-assembly at the liquid-solid interface

W. Song; N. Martsinovich; W. M. Heckl; M. Lackinger

doi:10.1039/c4cc06251e

Thermodynamics of halogen bonded monolayer self-assembly at the liquid-solid interface

W. Song, N. Martsinovich, W. M. Heckl, M. Lackinger

Lehrstuhl für Wissenschaftskommunikation

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

37 Zitate (Scopus)

Abstract

Monolayer self-assembly of a hexabrominated, three-fold symmetric aromatic molecule is studied at the heptanoic acid-graphite interface. Thermodynamical insights are obtained from an adapted Born-Haber cycle that is utilized to derive the overall enthalpy change including solvent effects. Comparison with theoretical entropy estimates suggests a minor influence of solvation.

Originalsprache	Englisch
Seiten (von - bis)	13465-13468
Seitenumfang	4
Fachzeitschrift	Chemical Communications
Jahrgang	50
Ausgabenummer	88
DOIs	https://doi.org/10.1039/c4cc06251e
Publikationsstatus	Veröffentlicht - 9 Okt. 2014

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10.1039/c4cc06251e

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title = "Thermodynamics of halogen bonded monolayer self-assembly at the liquid-solid interface",

abstract = "Monolayer self-assembly of a hexabrominated, three-fold symmetric aromatic molecule is studied at the heptanoic acid-graphite interface. Thermodynamical insights are obtained from an adapted Born-Haber cycle that is utilized to derive the overall enthalpy change including solvent effects. Comparison with theoretical entropy estimates suggests a minor influence of solvation.",

author = "W. Song and N. Martsinovich and Heckl, {W. M.} and M. Lackinger",

year = "2014",

month = oct,

day = "9",

doi = "10.1039/c4cc06251e",

language = "English",

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journal = "Chemical Communications",

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AU - Song, W.

AU - Martsinovich, N.

AU - Heckl, W. M.

AU - Lackinger, M.

PY - 2014/10/9

Y1 - 2014/10/9

N2 - Monolayer self-assembly of a hexabrominated, three-fold symmetric aromatic molecule is studied at the heptanoic acid-graphite interface. Thermodynamical insights are obtained from an adapted Born-Haber cycle that is utilized to derive the overall enthalpy change including solvent effects. Comparison with theoretical entropy estimates suggests a minor influence of solvation.

AB - Monolayer self-assembly of a hexabrominated, three-fold symmetric aromatic molecule is studied at the heptanoic acid-graphite interface. Thermodynamical insights are obtained from an adapted Born-Haber cycle that is utilized to derive the overall enthalpy change including solvent effects. Comparison with theoretical entropy estimates suggests a minor influence of solvation.

UR - http://www.scopus.com/inward/record.url?scp=84908011530&partnerID=8YFLogxK

U2 - 10.1039/c4cc06251e

DO - 10.1039/c4cc06251e

M3 - Article

C2 - 25236504

AN - SCOPUS:84908011530

SN - 1359-7345

VL - 50

SP - 13465

EP - 13468

JO - Chemical Communications

JF - Chemical Communications

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ER -

Thermodynamics of halogen bonded monolayer self-assembly at the liquid-solid interface

Abstract

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