The sudden-polarization effect and its role in the ultrafast photochemistry of ethene

Alexandra Viel; Robert P. Krawczyk; Uwe Manthe; Wolfgang Domcke

doi:10.1002/anie.200351193

The sudden-polarization effect and its role in the ultrafast photochemistry of ethene

Alexandra Viel, Robert P. Krawczyk, Uwe Manthe, Wolfgang Domcke

Lehrstuhl für Theoretische Chemie

Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

39 Zitate (Scopus)

Abstract

Surprisingly polar: The single-sided scissoring-induced sudden-polarization effect in D_2d ethene is first order (see picture). The important role of this coordinate was until now overlooked, although it was known for a long time that each geometrical distortion that leads to a breakage of the D_2d symmetry results in a charge separation.

Originalsprache	Englisch
Seiten (von - bis)	3434-3436
Seitenumfang	3
Fachzeitschrift	Angewandte Chemie International Edition in English
Jahrgang	42
Ausgabenummer	29
DOIs	https://doi.org/10.1002/anie.200351193
Publikationsstatus	Veröffentlicht - 28 Juli 2003

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abstract = "Surprisingly polar: The single-sided scissoring-induced sudden-polarization effect in D2d ethene is first order (see picture). The important role of this coordinate was until now overlooked, although it was known for a long time that each geometrical distortion that leads to a breakage of the D2d symmetry results in a charge separation.",

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AB - Surprisingly polar: The single-sided scissoring-induced sudden-polarization effect in D2d ethene is first order (see picture). The important role of this coordinate was until now overlooked, although it was known for a long time that each geometrical distortion that leads to a breakage of the D2d symmetry results in a charge separation.

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KW - Polarization effects

KW - Theoretical chemistry

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The sudden-polarization effect and its role in the ultrafast photochemistry of ethene

Abstract

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