The origin of the particle-size-dependent selectivity in 1-butene isomerization and hydrogenation on Pd/Al2O3 catalysts

Alexander Genest; Joaquín Silvestre-Albero; Wen Qing Li; Notker Rösch; Günther Rupprechter

doi:10.1038/s41467-021-26411-8

The origin of the particle-size-dependent selectivity in 1-butene isomerization and hydrogenation on Pd/Al₂O₃ catalysts

Alexander Genest, Joaquín Silvestre-Albero, Wen Qing Li, Notker Rösch, Günther Rupprechter

Professur für Theoretische Chemie (2008 — 2024)

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

19 Zitate (Scopus)

Abstract

The selectivity of 1-butene hydrogenation/isomerization on Pd catalysts is known to be particle size dependent. Here we show that combining well-defined model catalysts, atmospheric pressure reaction kinetics, DFT calculations and microkinetic modeling enables to rationalize the particle size effect based on the abundance and the specific properties of the contributing surface facets.

Originalsprache	Englisch
Aufsatznummer	6098
Fachzeitschrift	Nature Communications
Jahrgang	12
Ausgabenummer	1
DOIs	https://doi.org/10.1038/s41467-021-26411-8
Publikationsstatus	Veröffentlicht - 1 Dez. 2021

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10.1038/s41467-021-26411-8

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