The Complex Ions [C5H5M(CO)3]⊖ (MMo, W) as 6e‐Ligands: Synthesis and Molecular Structure of [(η4‐C4Me4)‐Co(μ‐CO)3M(η5)] (MMo, W)

Peter Härter; Heike Pfisterer; Manfred L. Ziegler

doi:10.1002/anie.198608391

The Complex Ions [C₅H₅M(CO)₃]^⊖ (MMo, W) as 6e‐Ligands: Synthesis and Molecular Structure of [(η⁴‐C₄Me₄)‐Co(μ‐CO)₃M(η⁵)] (MMo, W)

Peter Härter, Heike Pfisterer, Manfred L. Ziegler

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Heidelberg University

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

17 Zitate (Scopus)

Abstract

A model example for the isolobal analogy between the 6e‐donor [(C₅H₅)M(CO)₃]^⊖ and C₅H 5⊖ (see previous communication) is the title compund 2. It is formed upon thermal elimination of CO from 1. The symmetric coordination of the (C₅H₅)W(CO)₃ fragment has been confirmed by X‐ray structure analysis. (Figure Presented.)

Originalsprache	Englisch
Seiten (von - bis)	839-840
Seitenumfang	2
Fachzeitschrift	Angewandte Chemie International Edition in English
Jahrgang	25
Ausgabenummer	9
DOIs	https://doi.org/10.1002/anie.198608391
Publikationsstatus	Veröffentlicht - Sept. 1986

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abstract = "A model example for the isolobal analogy between the 6e‐donor [(C5H5)M(CO)3]⊖ and C5H 5⊖ (see previous communication) is the title compund 2. It is formed upon thermal elimination of CO from 1. The symmetric coordination of the (C5H5)W(CO)3 fragment has been confirmed by X‐ray structure analysis. (Figure Presented.)",

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AB - A model example for the isolobal analogy between the 6e‐donor [(C5H5)M(CO)3]⊖ and C5H 5⊖ (see previous communication) is the title compund 2. It is formed upon thermal elimination of CO from 1. The symmetric coordination of the (C5H5)W(CO)3 fragment has been confirmed by X‐ray structure analysis. (Figure Presented.)

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