Tetrakis[(triphenylphosphine)gold(I)](tricyclohexylphosphine)boronium tetrafluoroborate, a novel boron-centred gold cluster

Annette Blumenthal; Holger Beruda; Hubert Schmidbaur

doi:10.1039/C39930001005

Tetrakis[(triphenylphosphine)gold(I)](tricyclohexylphosphine)boronium tetrafluoroborate, a novel boron-centred gold cluster

Annette Blumenthal, Holger Beruda, Hubert Schmidbaur

Department Chemistry

Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

47 Zitate (Scopus)

Abstract

Treatment of tricyclohexylphosphine(trimethylsilyl)borane with tris[(triphenylphosphine)gold(I)]oxonium tetrafluoro-borate [in tetrahydrofuran (thf) at -78°C] affords moderate yields of the title compound [(Cy ₃P)B(AuPPh₃)₄]⁺ BF₄ ^-, the cation of which features pentacoordinate boron atoms in the centre of a (pseudo) square pyramid with the Cy ₃P ligand in the apical position (Cy = cyclohexyl).

Originalsprache	Englisch
Seiten (von - bis)	1005-1006
Seitenumfang	2
Fachzeitschrift	Journal of the Chemical Society, Chemical Communications
Ausgabenummer	12
DOIs	https://doi.org/10.1039/C39930001005
Publikationsstatus	Veröffentlicht - 1993

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title = "Tetrakis[(triphenylphosphine)gold(I)](tricyclohexylphosphine)boronium tetrafluoroborate, a novel boron-centred gold cluster",

abstract = "Treatment of tricyclohexylphosphine(trimethylsilyl)borane with tris[(triphenylphosphine)gold(I)]oxonium tetrafluoro-borate [in tetrahydrofuran (thf) at -78°C] affords moderate yields of the title compound [(Cy 3P)B(AuPPh3)4]+ BF4 -, the cation of which features pentacoordinate boron atoms in the centre of a (pseudo) square pyramid with the Cy 3P ligand in the apical position (Cy = cyclohexyl).",

author = "Annette Blumenthal and Holger Beruda and Hubert Schmidbaur",

year = "1993",

doi = "10.1039/C39930001005",

language = "English",

pages = "1005--1006",

journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Blumenthal, Annette

AU - Beruda, Holger

AU - Schmidbaur, Hubert

PY - 1993

Y1 - 1993

N2 - Treatment of tricyclohexylphosphine(trimethylsilyl)borane with tris[(triphenylphosphine)gold(I)]oxonium tetrafluoro-borate [in tetrahydrofuran (thf) at -78°C] affords moderate yields of the title compound [(Cy 3P)B(AuPPh3)4]+ BF4 -, the cation of which features pentacoordinate boron atoms in the centre of a (pseudo) square pyramid with the Cy 3P ligand in the apical position (Cy = cyclohexyl).

AB - Treatment of tricyclohexylphosphine(trimethylsilyl)borane with tris[(triphenylphosphine)gold(I)]oxonium tetrafluoro-borate [in tetrahydrofuran (thf) at -78°C] affords moderate yields of the title compound [(Cy 3P)B(AuPPh3)4]+ BF4 -, the cation of which features pentacoordinate boron atoms in the centre of a (pseudo) square pyramid with the Cy 3P ligand in the apical position (Cy = cyclohexyl).

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IS - 12

ER -

Tetrakis[(triphenylphosphine)gold(I)](tricyclohexylphosphine)boronium tetrafluoroborate, a novel boron-centred gold cluster

Abstract

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