Taming the germyliumylidene [CIGe:]+ and germathionium [CIGeS]+ ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene

Yun Xiong; Shenglai Yao; Shigeyoshi Inoue; Andreas Berkefeld; Matthias Driess

doi:10.1039/c2cc36926e

Taming the germyliumylidene [CIGe:]⁺ and germathionium [CIGeS]⁺ ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene

Yun Xiong, Shenglai Yao, Shigeyoshi Inoue, Andreas Berkefeld, Matthias Driess

Technische Universität Berlin

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

44 Zitate (Scopus)

Abstract

The novel chlorogermyliumylidene complex L[ClGe:]⁺ (L = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a “naked” Cl- as a counter anion was synthesized through reaction of L with Cl₂Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGeS]⁺ cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis.

Originalsprache	Englisch
Seiten (von - bis)	12198-12200
Seitenumfang	3
Fachzeitschrift	Chemical Communications
Jahrgang	48
Ausgabenummer	100
DOIs	https://doi.org/10.1039/c2cc36926e
Publikationsstatus	Veröffentlicht - 21 Nov. 2012
Extern publiziert	Ja

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10.1039/c2cc36926e

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abstract = "The novel chlorogermyliumylidene complex L[ClGe:]+ (L = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a “naked” Cl- as a counter anion was synthesized through reaction of L with Cl2Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGeS]+ cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis.",

author = "Yun Xiong and Shenglai Yao and Shigeyoshi Inoue and Andreas Berkefeld and Matthias Driess",

year = "2012",

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T1 - Taming the germyliumylidene [CIGe:]+ and germathionium [CIGeS]+ ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene

AU - Xiong, Yun

AU - Yao, Shenglai

AU - Inoue, Shigeyoshi

AU - Berkefeld, Andreas

AU - Driess, Matthias

PY - 2012/11/21

Y1 - 2012/11/21

N2 - The novel chlorogermyliumylidene complex L[ClGe:]+ (L = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a “naked” Cl- as a counter anion was synthesized through reaction of L with Cl2Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGeS]+ cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis.

AB - The novel chlorogermyliumylidene complex L[ClGe:]+ (L = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a “naked” Cl- as a counter anion was synthesized through reaction of L with Cl2Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGeS]+ cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis.

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