Synthesis of a cyclopentadienyl(imino)stannylene and its direct conversion into halo(imino)stannylenes

Tatsumi Ochiai; Shigeyoshi Inoue

doi:10.1039/c6ra27697k

Synthesis of a cyclopentadienyl(imino)stannylene and its direct conversion into halo(imino)stannylenes

Tatsumi Ochiai, Shigeyoshi Inoue

Professur für Siliciumchemie

Technische Universität Berlin

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

16 Zitate (Scopus)

Abstract

The reaction of stannocene Cp₂Sn with iminolithium LiNIPr (NIPr = bis(2,6-diisopropylphenyl)imidazolin-2-iminato) afforded the dimeric cyclopentadienyl(imino)stannylene [(η¹-Cp)SnNIPr]₂ (1). Compound 1 exhibits unexpected reactivity towards haloalkanes. The high-yield conversion of 1 into chlorostannylene [ClSnNIPr]₂ (2) and bromostannylene [BrSnNIPr]₂ (3) were accomplished by treatment with dichloromethane or 1,2-dibromoethane, respectively, through a Cp-substitution reaction.

Originalsprache	Englisch
Seiten (von - bis)	801-804
Seitenumfang	4
Fachzeitschrift	RSC Advances
Jahrgang	7
Ausgabenummer	2
DOIs	https://doi.org/10.1039/c6ra27697k
Publikationsstatus	Veröffentlicht - 2017

Zugriff auf Dokument

10.1039/c6ra27697k

Andere Dateien und Links

Verknüpfung zur Publikation in Scopus

Dieses zitieren

@article{3ca4438ab6094f139b3e2b7cb743399a,

title = "Synthesis of a cyclopentadienyl(imino)stannylene and its direct conversion into halo(imino)stannylenes",

abstract = "The reaction of stannocene Cp2Sn with iminolithium LiNIPr (NIPr = bis(2,6-diisopropylphenyl)imidazolin-2-iminato) afforded the dimeric cyclopentadienyl(imino)stannylene [(η1-Cp)SnNIPr]2 (1). Compound 1 exhibits unexpected reactivity towards haloalkanes. The high-yield conversion of 1 into chlorostannylene [ClSnNIPr]2 (2) and bromostannylene [BrSnNIPr]2 (3) were accomplished by treatment with dichloromethane or 1,2-dibromoethane, respectively, through a Cp-substitution reaction.",

author = "Tatsumi Ochiai and Shigeyoshi Inoue",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c6ra27697k",

language = "English",

volume = "7",

pages = "801--804",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - Synthesis of a cyclopentadienyl(imino)stannylene and its direct conversion into halo(imino)stannylenes

AU - Ochiai, Tatsumi

AU - Inoue, Shigeyoshi

PY - 2017

Y1 - 2017

N2 - The reaction of stannocene Cp2Sn with iminolithium LiNIPr (NIPr = bis(2,6-diisopropylphenyl)imidazolin-2-iminato) afforded the dimeric cyclopentadienyl(imino)stannylene [(η1-Cp)SnNIPr]2 (1). Compound 1 exhibits unexpected reactivity towards haloalkanes. The high-yield conversion of 1 into chlorostannylene [ClSnNIPr]2 (2) and bromostannylene [BrSnNIPr]2 (3) were accomplished by treatment with dichloromethane or 1,2-dibromoethane, respectively, through a Cp-substitution reaction.

AB - The reaction of stannocene Cp2Sn with iminolithium LiNIPr (NIPr = bis(2,6-diisopropylphenyl)imidazolin-2-iminato) afforded the dimeric cyclopentadienyl(imino)stannylene [(η1-Cp)SnNIPr]2 (1). Compound 1 exhibits unexpected reactivity towards haloalkanes. The high-yield conversion of 1 into chlorostannylene [ClSnNIPr]2 (2) and bromostannylene [BrSnNIPr]2 (3) were accomplished by treatment with dichloromethane or 1,2-dibromoethane, respectively, through a Cp-substitution reaction.

UR - http://www.scopus.com/inward/record.url?scp=85008932565&partnerID=8YFLogxK

U2 - 10.1039/c6ra27697k

DO - 10.1039/c6ra27697k

M3 - Article

AN - SCOPUS:85008932565

SN - 2046-2069

VL - 7

SP - 801

EP - 804

JO - RSC Advances

JF - RSC Advances

IS - 2

ER -

Synthesis of a cyclopentadienyl(imino)stannylene and its direct conversion into halo(imino)stannylenes

Abstract

Zugriff auf Dokument

Andere Dateien und Links

Fingerprint

Dieses zitieren