Abstract
The superposition of scalar and residual dipolar couplings gives rise to so-called cylindrical mixing Hamiltonians in dipolar coupling spectroscopy. General analytical polarization and coherence transfer functions are presented for three cylindrically coupled spins 1/2 under energy-matched conditions. In addition, the transfer efficiency is analyzed as a function of the relative coupling constants for characteristic special cases.
Originalsprache | Englisch |
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Seiten (von - bis) | 169-181 |
Seitenumfang | 13 |
Fachzeitschrift | Journal of Magnetic Resonance |
Jahrgang | 148 |
Ausgabenummer | 1 |
DOIs | |
Publikationsstatus | Veröffentlicht - 2001 |