Stretched poly(vinyl acetate) gels as NMR alignment media for the measurement of residual dipolar couplings in polar organic solvents

J. Christoph Freudenberger, Sebastian Knör, Kyryl Kobzar, Dominik Heckmann, Thomas Paululat, Horst Kessler, Burkhard Luy

Publikation: Beitrag in FachzeitschriftArtikelBegutachtung

71 Zitate (Scopus)

Abstract

Partial alignment of molecules in polar organic solvents for the measurement of residual dipolar couplings (RDCs) in high-resolution NMR spectroscopy can be achieved by stretched poly(vinyl acetate) gels. The method opens the door of RDC-derived structural information (e.g. from DCH couplings, see picture) to new classes of molecules by closing the existing gap between apolar and aqueous solutions. (Figure Presented).

OriginalspracheEnglisch
Seiten (von - bis)423-426
Seitenumfang4
FachzeitschriftAngewandte Chemie International Edition in English
Jahrgang44
Ausgabenummer3
DOIs
PublikationsstatusVeröffentlicht - 3 Jan. 2005

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