Selective oxidative cleavage of Cp from coordinated GaCp: Naked Ga in [GaNi(GaCp)4]+ and [(μ2-Ga) nM3(GaCp)6]n+

Markus Halbherr; Timo Bollermann; Christian Gemel; Roland A. Fischer

doi:10.1002/anie.200905920

Selective oxidative cleavage of Cp from coordinated GaCp: Naked Ga in [GaNi(GaCp)₄]⁺ and [(μ₂-Ga) _nM₃(GaCp)₆]ⁿ⁺

Markus Halbherr, Timo Bollermann, Christian Gemel, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

16 Zitate (Scopus)

Abstract

(Chemical Equation Presentstion) The naked and the edge: The selective oxidative cleavage of Cp from coordinated CaCp ligands lead to the cluster cations [(μ₂-Ga)₂Pd₃(GaCp)₆] ²⁺ and [(μ₂Ga)Pt₃(GaCp)₆] ⁺ (see structure) which are the first examples of the edge-bridging coordination mode of "naked" Ga⁺. This chemistry is a step towards a rational synthesis of metal-rich molecules as discrete models for intermetallic phases.

Originalsprache	Englisch
Seiten (von - bis)	1878-1881
Seitenumfang	4
Fachzeitschrift	Angewandte Chemie International Edition in English
Jahrgang	49
Ausgabenummer	10
DOIs	https://doi.org/10.1002/anie.200905920
Publikationsstatus	Veröffentlicht - 1 März 2010
Extern publiziert	Ja

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10.1002/anie.200905920

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abstract = "(Chemical Equation Presentstion) The naked and the edge: The selective oxidative cleavage of Cp from coordinated CaCp ligands lead to the cluster cations [(μ2-Ga)2Pd3(GaCp)6] 2+ and [(μ2Ga)Pt3(GaCp)6] + (see structure) which are the first examples of the edge-bridging coordination mode of {"}naked{"} Ga+. This chemistry is a step towards a rational synthesis of metal-rich molecules as discrete models for intermetallic phases.",

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T2 - Naked Ga in [GaNi(GaCp)4]+ and [(μ2-Ga) nM3(GaCp)6]n+

AU - Halbherr, Markus

AU - Bollermann, Timo

AU - Gemel, Christian

AU - Fischer, Roland A.

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AB - (Chemical Equation Presentstion) The naked and the edge: The selective oxidative cleavage of Cp from coordinated CaCp ligands lead to the cluster cations [(μ2-Ga)2Pd3(GaCp)6] 2+ and [(μ2Ga)Pt3(GaCp)6] + (see structure) which are the first examples of the edge-bridging coordination mode of "naked" Ga+. This chemistry is a step towards a rational synthesis of metal-rich molecules as discrete models for intermetallic phases.

KW - Carbenoids

KW - Cluster compounds

KW - Gallium

KW - Group 13 elements

KW - Oxidation state

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