Sc(OTf)₃-catalyzed diastereoselective Friedel-Crafts reactions of arenes and hetarenes with 3-phenylglycidates

Keyphrases

• Arenes 100%
• Benzylic 100%
• Diastereoselective 100%
• Friedel-Crafts Reaction 100%
• Sc(OTf)3 100%
• Hetarenes 100%
• Nucleophile 50%
• Carboxylate 50%
• Preferred Conformation 50%
• Tert-butyl 50%
• Diastereoselectivity 50%
• Stereogenic Centers 50%
• Diastereomeric Ratio 50%
• Lewis Acid Catalysis 50%
• Phenyloxirane 50%
• Nitromethane 50%

Chemistry

• Friedel-Crafts Reaction 100%
• Diastereomer 50%
• Lewis Acid 50%
• Diastereoselectivity 50%
• Acid Catalysis 50%
• Nitromethane 50%
• Nucleophile 50%
• Carboxylic Acid 50%