Reactions of water clusters H+(H2O)n, n = 3-75, with diethyl ether

Thomas Schindler; Christian Berg; Gereon Niedner-Schatteburg; Vladimir E. Bondybey

doi:10.1016/0301-0104(95)00288-X

Reactions of water clusters H⁺(H₂O)_n, n = 3-75, with diethyl ether

Thomas Schindler, Christian Berg, Gereon Niedner-Schatteburg, Vladimir E. Bondybey

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Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

14 Zitate (Scopus)

Abstract

Fragmentation and ligand exchange reactions of protonated water clusters H⁺(H₂O)_n, n = 3-75 with diethyl ether were investigated in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The reactions proceed efficiently until the water core is completely "coated" by an outer layer of organic ether molecules, and relatively stable ions with H⁺(H₂O)_m[(C₂H₅)₂O]_m+2 composition are formed. These further react on a much longer time scale towards the H⁺[(C₂H₅)₂O]₂ (m = 0) final product ion.

Originalsprache	Englisch
Seiten (von - bis)	491-496
Seitenumfang	6
Fachzeitschrift	Chemical Physics
Jahrgang	201
Ausgabenummer	2-3
DOIs	https://doi.org/10.1016/0301-0104(95)00288-X
Publikationsstatus	Veröffentlicht - 15 Dez. 1995

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title = "Reactions of water clusters H+(H2O)n, n = 3-75, with diethyl ether",

abstract = "Fragmentation and ligand exchange reactions of protonated water clusters H+(H2O)n, n = 3-75 with diethyl ether were investigated in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The reactions proceed efficiently until the water core is completely {"}coated{"} by an outer layer of organic ether molecules, and relatively stable ions with H+(H2O)m[(C2H5)2O]m+2 composition are formed. These further react on a much longer time scale towards the H+[(C2H5)2O]2 (m = 0) final product ion.",

author = "Thomas Schindler and Christian Berg and Gereon Niedner-Schatteburg and Bondybey, {Vladimir E.}",

note = "Funding Information: Financial support by the Deutsche Forschungsge-meinschaft, by the Fonds der Chemischen Industrie and by the Commission of the European Union, program Human Capital and Mobility, is gratefully acknowledged.",

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AU - Schindler, Thomas

AU - Berg, Christian

AU - Niedner-Schatteburg, Gereon

AU - Bondybey, Vladimir E.

N1 - Funding Information: Financial support by the Deutsche Forschungsge-meinschaft, by the Fonds der Chemischen Industrie and by the Commission of the European Union, program Human Capital and Mobility, is gratefully acknowledged.

PY - 1995/12/15

Y1 - 1995/12/15

N2 - Fragmentation and ligand exchange reactions of protonated water clusters H+(H2O)n, n = 3-75 with diethyl ether were investigated in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The reactions proceed efficiently until the water core is completely "coated" by an outer layer of organic ether molecules, and relatively stable ions with H+(H2O)m[(C2H5)2O]m+2 composition are formed. These further react on a much longer time scale towards the H+[(C2H5)2O]2 (m = 0) final product ion.

AB - Fragmentation and ligand exchange reactions of protonated water clusters H+(H2O)n, n = 3-75 with diethyl ether were investigated in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The reactions proceed efficiently until the water core is completely "coated" by an outer layer of organic ether molecules, and relatively stable ions with H+(H2O)m[(C2H5)2O]m+2 composition are formed. These further react on a much longer time scale towards the H+[(C2H5)2O]2 (m = 0) final product ion.

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