Quantum cryo-sieving for hydrogen isotope separation in microporous frameworks: An experimental study on the correlation between effective quantum sieving and pore size

Hyunchul Oh; Kyo Sung Park; Suresh Babu Kalidindi; Roland A. Fischer; Michael Hirscher

doi:10.1039/c3ta01544k

Quantum cryo-sieving for hydrogen isotope separation in microporous frameworks: An experimental study on the correlation between effective quantum sieving and pore size

Hyunchul Oh, Kyo Sung Park, Suresh Babu Kalidindi, Roland A. Fischer, Michael Hirscher

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

75 Zitate (Scopus)

Abstract

Different microporous frameworks have been experimentally investigated by cryogenic (below 77 K) hydrogen and deuterium adsorption measurements. The D₂/H₂ molar ratio is strongly dependent on pore size, pressure and temperature. The experiments clearly indicate that the optimum pore diameter for quantum sieving lies between 3.0 Å and 3.4 Å.

Originalsprache	Englisch
Seiten (von - bis)	3244-3248
Seitenumfang	5
Fachzeitschrift	Journal of Materials Chemistry A
Jahrgang	1
Ausgabenummer	10
DOIs	https://doi.org/10.1039/c3ta01544k
Publikationsstatus	Veröffentlicht - 14 März 2013
Extern publiziert	Ja

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abstract = "Different microporous frameworks have been experimentally investigated by cryogenic (below 77 K) hydrogen and deuterium adsorption measurements. The D2/H2 molar ratio is strongly dependent on pore size, pressure and temperature. The experiments clearly indicate that the optimum pore diameter for quantum sieving lies between 3.0 {\AA} and 3.4 {\AA}.",

author = "Hyunchul Oh and Park, {Kyo Sung} and Kalidindi, {Suresh Babu} and Fischer, {Roland A.} and Michael Hirscher",

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Quantum cryo-sieving for hydrogen isotope separation in microporous frameworks: An experimental study on the correlation between effective quantum sieving and pore size. / Oh, Hyunchul; Park, Kyo Sung; Kalidindi, Suresh Babu et al.
in: Journal of Materials Chemistry A, Jahrgang 1, Nr. 10, 14.03.2013, S. 3244-3248.

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

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T2 - An experimental study on the correlation between effective quantum sieving and pore size

AU - Oh, Hyunchul

AU - Park, Kyo Sung

AU - Kalidindi, Suresh Babu

AU - Fischer, Roland A.

AU - Hirscher, Michael

PY - 2013/3/14

Y1 - 2013/3/14

N2 - Different microporous frameworks have been experimentally investigated by cryogenic (below 77 K) hydrogen and deuterium adsorption measurements. The D2/H2 molar ratio is strongly dependent on pore size, pressure and temperature. The experiments clearly indicate that the optimum pore diameter for quantum sieving lies between 3.0 Å and 3.4 Å.

AB - Different microporous frameworks have been experimentally investigated by cryogenic (below 77 K) hydrogen and deuterium adsorption measurements. The D2/H2 molar ratio is strongly dependent on pore size, pressure and temperature. The experiments clearly indicate that the optimum pore diameter for quantum sieving lies between 3.0 Å and 3.4 Å.

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JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

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Quantum cryo-sieving for hydrogen isotope separation in microporous frameworks: An experimental study on the correlation between effective quantum sieving and pore size

Abstract

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