Polygold(1-adamantyl)ammonium salts

José M. López-de-Luzuriaga; Annette Schier; Hubert Schmidbaur

doi:10.1002/cber.19971300213

Polygold(1-adamantyl)ammonium salts

José M. López-de-Luzuriaga, Annette Schier, Hubert Schmidbaur

Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

12 Zitate (Scopus)

Abstract

The reaction of 1-adamantylamine with tris(triphenylphosphaneauriojoxonium tetrafluoroborate results in the formation of the trinuclear adamantyltrisftriphenylphosphaneaurio)ammonium tetrafluoroborate (C₁₀H₁₅N[Au(PPh₃)]₃) ⁺BF₄^-. The product can be further aurated by addition of equimolar amounts of triphenylphosphanegold(I) tetrafluoroborate to give the tetranuclear complex (C₁₀H₁₅N[Au(PPh₃)]₄) ²⁺{BF₄^-)₂. Both compounds have been fully characterized by analytical and spectroscopic data, and in the case of the trinuclear complex by a single crystal X-ray structure determination.

Originalsprache	Englisch
Seiten (von - bis)	221-223
Seitenumfang	3
Fachzeitschrift	Chemische Berichte
Jahrgang	130
Ausgabenummer	2
DOIs	https://doi.org/10.1002/cber.19971300213
Publikationsstatus	Veröffentlicht - 1997
Extern publiziert	Ja

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title = "Polygold(1-adamantyl)ammonium salts",

abstract = "The reaction of 1-adamantylamine with tris(triphenylphosphaneauriojoxonium tetrafluoroborate results in the formation of the trinuclear adamantyltrisftriphenylphosphaneaurio)ammonium tetrafluoroborate (C10H15N[Au(PPh3)]3) +BF4-. The product can be further aurated by addition of equimolar amounts of triphenylphosphanegold(I) tetrafluoroborate to give the tetranuclear complex (C10H15N[Au(PPh3)]4) 2+{BF4-)2. Both compounds have been fully characterized by analytical and spectroscopic data, and in the case of the trinuclear complex by a single crystal X-ray structure determination.",

keywords = "(1-Adamantyl)ammonium salts, Gold, Polygoldammonium salts, Tetranuclear complex, Trinuclear complex, X-cay structure of",

author = "L{\'o}pez-de-Luzuriaga, {Jos{\'e} M.} and Annette Schier and Hubert Schmidbaur",

year = "1997",

doi = "10.1002/cber.19971300213",

language = "English",

volume = "130",

pages = "221--223",

journal = "Chemische Berichte",

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TY - JOUR

T1 - Polygold(1-adamantyl)ammonium salts

AU - López-de-Luzuriaga, José M.

AU - Schier, Annette

AU - Schmidbaur, Hubert

PY - 1997

Y1 - 1997

N2 - The reaction of 1-adamantylamine with tris(triphenylphosphaneauriojoxonium tetrafluoroborate results in the formation of the trinuclear adamantyltrisftriphenylphosphaneaurio)ammonium tetrafluoroborate (C10H15N[Au(PPh3)]3) +BF4-. The product can be further aurated by addition of equimolar amounts of triphenylphosphanegold(I) tetrafluoroborate to give the tetranuclear complex (C10H15N[Au(PPh3)]4) 2+{BF4-)2. Both compounds have been fully characterized by analytical and spectroscopic data, and in the case of the trinuclear complex by a single crystal X-ray structure determination.

AB - The reaction of 1-adamantylamine with tris(triphenylphosphaneauriojoxonium tetrafluoroborate results in the formation of the trinuclear adamantyltrisftriphenylphosphaneaurio)ammonium tetrafluoroborate (C10H15N[Au(PPh3)]3) +BF4-. The product can be further aurated by addition of equimolar amounts of triphenylphosphanegold(I) tetrafluoroborate to give the tetranuclear complex (C10H15N[Au(PPh3)]4) 2+{BF4-)2. Both compounds have been fully characterized by analytical and spectroscopic data, and in the case of the trinuclear complex by a single crystal X-ray structure determination.

KW - (1-Adamantyl)ammonium salts

KW - Gold

KW - Polygoldammonium salts

KW - Tetranuclear complex

KW - Trinuclear complex, X-cay structure of

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U2 - 10.1002/cber.19971300213

DO - 10.1002/cber.19971300213

M3 - Article

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EP - 223

JO - Chemische Berichte

JF - Chemische Berichte

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Polygold(1-adamantyl)ammonium salts

Abstract

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