Photon energy dependence of satelite line intensity in the photoelectron spectrum of acetylene

A. M. Bradshaw, W. Eberhardt, H. J. Levinson, W. Domcke, L. S. Cederbaum

Publikation: Beitrag in FachzeitschriftArtikelBegutachtung

40 Zitate (Scopus)

Abstract

The intensity of the satellite at 27.5 eV ionisation energy in the photoelectron spectrum of acetylene has been studied as a function of photon energy using synchrotron radiation. In the accessible range up to h{stroke}ω = 72 eV, the satellite is considerably weaker relative to the 2σg main line than at h{stroke}ω = 151 and 1254 eV. If the satellite is indeed of 2Σg symmetry, as both theory and c-2c experiments show, then the effect can be attributed to interference between 2σg- and 3σg-derived components of the spectral function.

OriginalspracheEnglisch
Seiten (von - bis)36-40
Seitenumfang5
FachzeitschriftChemical Physics Letters
Jahrgang70
Ausgabenummer1
DOIs
PublikationsstatusVeröffentlicht - 15 Feb. 1980

Fingerprint

Untersuchen Sie die Forschungsthemen von „Photon energy dependence of satelite line intensity in the photoelectron spectrum of acetylene“. Zusammen bilden sie einen einzigartigen Fingerprint.

Dieses zitieren