Patterned Diblock Co-Polymer Thin Films as Templates for Advanced Anisotropic Metal Nanostructures

Stephan V. Roth; Gonzalo Santoro; Johannes F.H. Risch; Shun Yu; Matthias Schwartzkopf; Torsten Boese; Ralph Döhrmann; Peng Zhang; Bastian Besner; Philipp Bremer; Dieter Rukser; Michael A. Rübhausen; Nick J. Terrill; Paul A. Staniec; Yuan Yao; Ezzeldin Metwalli; Peter Müller-Buschbaum

doi:10.1021/am507727f

Patterned Diblock Co-Polymer Thin Films as Templates for Advanced Anisotropic Metal Nanostructures

Stephan V. Roth, Gonzalo Santoro, Johannes F.H. Risch, Shun Yu, Matthias Schwartzkopf, Torsten Boese, Ralph Döhrmann, Peng Zhang, Bastian Besner, Philipp Bremer, Dieter Rukser, Michael A. Rübhausen, Nick J. Terrill, Paul A. Staniec, Yuan Yao, Ezzeldin Metwalli, Peter Müller-Buschbaum

Lehrstuhl für Funktionelle Materialien

Publikation: Beitrag in Fachzeitschrift › Übersichtsartikel › Begutachtung

63 Zitate (Scopus)

Abstract

We demonstrate glancing-angle deposition of gold on a nanostructured diblock copolymer, namely polystyrene-block-poly(methyl methacrylate) thin film. Exploiting the selective wetting of gold on the polystyrene block, we are able to fabricate directional hierarchical structures. We prove the asymmetric growth of the gold nanoparticles and are able to extract the different growth laws by in situ scattering methods. The optical anisotropy of these hierarchical hybrid materials is further probed by angular resolved spectroscopic methods. This approach enables us to tailor functional hierarchical layers in nanodevices, such as nanoantennae arrays, organic photovoltaics, and sensor electronics.

Originalsprache	Englisch
Seiten (von - bis)	12470-12477
Seitenumfang	8
Fachzeitschrift	ACS Applied Materials and Interfaces
Jahrgang	7
Ausgabenummer	23
DOIs	https://doi.org/10.1021/am507727f
Publikationsstatus	Veröffentlicht - 17 Juni 2015

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10.1021/am507727f

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Roth, S. V., Santoro, G., Risch, J. F. H., Yu, S., Schwartzkopf, M., Boese, T., Döhrmann, R., Zhang, P., Besner, B., Bremer, P., Rukser, D., Rübhausen, M. A., Terrill, N. J., Staniec, P. A., Yao, Y., Metwalli, E., & Müller-Buschbaum, P. (2015). Patterned Diblock Co-Polymer Thin Films as Templates for Advanced Anisotropic Metal Nanostructures. ACS Applied Materials and Interfaces, 7(23), 12470-12477. https://doi.org/10.1021/am507727f

@article{0f4f68b2769940b3a16672c60449378b,

title = "Patterned Diblock Co-Polymer Thin Films as Templates for Advanced Anisotropic Metal Nanostructures",

abstract = "We demonstrate glancing-angle deposition of gold on a nanostructured diblock copolymer, namely polystyrene-block-poly(methyl methacrylate) thin film. Exploiting the selective wetting of gold on the polystyrene block, we are able to fabricate directional hierarchical structures. We prove the asymmetric growth of the gold nanoparticles and are able to extract the different growth laws by in situ scattering methods. The optical anisotropy of these hierarchical hybrid materials is further probed by angular resolved spectroscopic methods. This approach enables us to tailor functional hierarchical layers in nanodevices, such as nanoantennae arrays, organic photovoltaics, and sensor electronics.",

keywords = "diblock copolymer thin films, glancing angle deposition, grazing incidence scattering, hierarchical materials, nanocomposites",

author = "Roth, {Stephan V.} and Gonzalo Santoro and Risch, {Johannes F.H.} and Shun Yu and Matthias Schwartzkopf and Torsten Boese and Ralph D{\"o}hrmann and Peng Zhang and Bastian Besner and Philipp Bremer and Dieter Rukser and R{\"u}bhausen, {Michael A.} and Terrill, {Nick J.} and Staniec, {Paul A.} and Yuan Yao and Ezzeldin Metwalli and Peter M{\"u}ller-Buschbaum",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = jun,

day = "17",

doi = "10.1021/am507727f",

language = "English",

volume = "7",

pages = "12470--12477",

journal = "ACS Applied Materials and Interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

number = "23",

}

Roth, SV, Santoro, G, Risch, JFH, Yu, S, Schwartzkopf, M, Boese, T, Döhrmann, R, Zhang, P, Besner, B, Bremer, P, Rukser, D, Rübhausen, MA, Terrill, NJ, Staniec, PA, Yao, Y, Metwalli, E & Müller-Buschbaum, P 2015, 'Patterned Diblock Co-Polymer Thin Films as Templates for Advanced Anisotropic Metal Nanostructures', ACS Applied Materials and Interfaces, Jg. 7, Nr. 23, S. 12470-12477. https://doi.org/10.1021/am507727f

TY - JOUR

T1 - Patterned Diblock Co-Polymer Thin Films as Templates for Advanced Anisotropic Metal Nanostructures

AU - Roth, Stephan V.

AU - Santoro, Gonzalo

AU - Risch, Johannes F.H.

AU - Yu, Shun

AU - Schwartzkopf, Matthias

AU - Boese, Torsten

AU - Döhrmann, Ralph

AU - Zhang, Peng

AU - Besner, Bastian

AU - Bremer, Philipp

AU - Rukser, Dieter

AU - Rübhausen, Michael A.

AU - Terrill, Nick J.

AU - Staniec, Paul A.

AU - Yao, Yuan

AU - Metwalli, Ezzeldin

AU - Müller-Buschbaum, Peter

PY - 2015/6/17

Y1 - 2015/6/17

N2 - We demonstrate glancing-angle deposition of gold on a nanostructured diblock copolymer, namely polystyrene-block-poly(methyl methacrylate) thin film. Exploiting the selective wetting of gold on the polystyrene block, we are able to fabricate directional hierarchical structures. We prove the asymmetric growth of the gold nanoparticles and are able to extract the different growth laws by in situ scattering methods. The optical anisotropy of these hierarchical hybrid materials is further probed by angular resolved spectroscopic methods. This approach enables us to tailor functional hierarchical layers in nanodevices, such as nanoantennae arrays, organic photovoltaics, and sensor electronics.

AB - We demonstrate glancing-angle deposition of gold on a nanostructured diblock copolymer, namely polystyrene-block-poly(methyl methacrylate) thin film. Exploiting the selective wetting of gold on the polystyrene block, we are able to fabricate directional hierarchical structures. We prove the asymmetric growth of the gold nanoparticles and are able to extract the different growth laws by in situ scattering methods. The optical anisotropy of these hierarchical hybrid materials is further probed by angular resolved spectroscopic methods. This approach enables us to tailor functional hierarchical layers in nanodevices, such as nanoantennae arrays, organic photovoltaics, and sensor electronics.

KW - diblock copolymer thin films

KW - glancing angle deposition

KW - grazing incidence scattering

KW - hierarchical materials

KW - nanocomposites

UR - http://www.scopus.com/inward/record.url?scp=84932608527&partnerID=8YFLogxK

U2 - 10.1021/am507727f

DO - 10.1021/am507727f

M3 - Review article

AN - SCOPUS:84932608527

SN - 1944-8244

VL - 7

SP - 12470

EP - 12477

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

IS - 23

ER -

Patterned Diblock Co-Polymer Thin Films as Templates for Advanced Anisotropic Metal Nanostructures

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