NHC-stabilized silyl-substituted silyliumylidene ions

Philipp Frisch; Shigeyoshi Inoue

doi:10.1039/c9dt02010a

NHC-stabilized silyl-substituted silyliumylidene ions

Philipp Frisch, Shigeyoshi Inoue

Professur für Siliciumchemie

Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

10 Zitate (Scopus)

Abstract

The first silyl-substituted silyliumylidene ions are reported. The scope of a previously described convenient one-step procedure for the preparation of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions via dehydrochlorination from a Si(iv) precursor with NHCs is expanded to silyl-based substituents as well as aryl substituents with reduced steric bulk.

Originalsprache	Englisch
Seiten (von - bis)	10403-10406
Seitenumfang	4
Fachzeitschrift	Dalton Transactions
Jahrgang	48
Ausgabenummer	28
DOIs	https://doi.org/10.1039/c9dt02010a
Publikationsstatus	Veröffentlicht - 2019

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10.1039/c9dt02010a

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title = "NHC-stabilized silyl-substituted silyliumylidene ions",

abstract = "The first silyl-substituted silyliumylidene ions are reported. The scope of a previously described convenient one-step procedure for the preparation of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions via dehydrochlorination from a Si(iv) precursor with NHCs is expanded to silyl-based substituents as well as aryl substituents with reduced steric bulk.",

author = "Philipp Frisch and Shigeyoshi Inoue",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9dt02010a",

language = "English",

volume = "48",

pages = "10403--10406",

journal = "Dalton Transactions",

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AU - Frisch, Philipp

AU - Inoue, Shigeyoshi

PY - 2019

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N2 - The first silyl-substituted silyliumylidene ions are reported. The scope of a previously described convenient one-step procedure for the preparation of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions via dehydrochlorination from a Si(iv) precursor with NHCs is expanded to silyl-based substituents as well as aryl substituents with reduced steric bulk.

AB - The first silyl-substituted silyliumylidene ions are reported. The scope of a previously described convenient one-step procedure for the preparation of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions via dehydrochlorination from a Si(iv) precursor with NHCs is expanded to silyl-based substituents as well as aryl substituents with reduced steric bulk.

UR - http://www.scopus.com/inward/record.url?scp=85069196846&partnerID=8YFLogxK

U2 - 10.1039/c9dt02010a

DO - 10.1039/c9dt02010a

M3 - Article

C2 - 31241091

AN - SCOPUS:85069196846

SN - 1477-9226

VL - 48

SP - 10403

EP - 10406

JO - Dalton Transactions

JF - Dalton Transactions

IS - 28

ER -

NHC-stabilized silyl-substituted silyliumylidene ions

Abstract

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