TY - JOUR
T1 - N-heterocyclic carbene complexes of palladium and rhodium
T2 - Cis / trans-isomers
AU - Herrmann, Wolfgang A.
AU - Fischer, Jakob
AU - Öfele, Karl
AU - Artus, Georg R.J.
PY - 1997/3/1
Y1 - 1997/3/1
N2 - Stable carbene complexes of palladium or rhodium are readily accessible by (i) reaction of imidazolium or triazolium salts with palladium complexes bearing basic ligands or rhodium alkoxide complexes, (ii) adduct formation of the free carbene, e.g. 1,3-dimethylimidazoline-2-ylidene, with metal compounds. In the case of palladium(II) and rhodium(I), the resulting complexes show cis/trans-isomerization and can be compared to analogous phosphine complexes.
AB - Stable carbene complexes of palladium or rhodium are readily accessible by (i) reaction of imidazolium or triazolium salts with palladium complexes bearing basic ligands or rhodium alkoxide complexes, (ii) adduct formation of the free carbene, e.g. 1,3-dimethylimidazoline-2-ylidene, with metal compounds. In the case of palladium(II) and rhodium(I), the resulting complexes show cis/trans-isomerization and can be compared to analogous phosphine complexes.
KW - Cis / trans-isomerism
KW - N-Heterocyclic carbenes
KW - Palladium complexes
KW - Rhodium complexes
UR - http://www.scopus.com/inward/record.url?scp=0031093942&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(96)06892-1
DO - 10.1016/S0022-328X(96)06892-1
M3 - Article
AN - SCOPUS:0031093942
SN - 0022-328X
VL - 530
SP - 259
EP - 262
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-2
ER -