TY - JOUR
T1 - Mixed-ligand complexes of technetium IX. Oxidative ligand exchange reactions on tetraphenylarsonium-bis(dithiooxalato)nitridotechnetate(V), (Ph4As)2[TcN(dto)2]. X-ray crystal structure of a further modification of (Ph4As)2[TcN(dto)2]
AU - Abram, U.
AU - Münze, R.
AU - Kirmse, R.
AU - Köhler, K.
AU - Dietzsch, W.
AU - Golič, L.
PY - 1990/3/1
Y1 - 1990/3/1
N2 - (Ph4As)2[TcN(dto)2] can be prepared starting from TcNCl4- or TcNCl2(Ph3P)2. The compound crystallizes in at least two modifications: as well as a triclinic form (S. F. Colmanet and M. F. Mackay, Inorg. Chim. Acta, 147 (1988) 173) a monoclinic one has been found (space group C2/c, Z = 4, a = 19.424(3), b = 11.254(2), c = 24.958(3) Å, β = 107.68(1)°; R = 0.048). Distances and angles in the complex anions in both modifications are almost identical within experimental error. Oxidation of [TcN(dto)2]2- by Cl2 produces the Tc(VI) complex TcNCl4- exclusively, whereas during the Br2 oxidation technetium(VI) intermediates are generated containing mixed Br/dto coordination spheres which can be monitored easily by EPR spectroscopy.
AB - (Ph4As)2[TcN(dto)2] can be prepared starting from TcNCl4- or TcNCl2(Ph3P)2. The compound crystallizes in at least two modifications: as well as a triclinic form (S. F. Colmanet and M. F. Mackay, Inorg. Chim. Acta, 147 (1988) 173) a monoclinic one has been found (space group C2/c, Z = 4, a = 19.424(3), b = 11.254(2), c = 24.958(3) Å, β = 107.68(1)°; R = 0.048). Distances and angles in the complex anions in both modifications are almost identical within experimental error. Oxidation of [TcN(dto)2]2- by Cl2 produces the Tc(VI) complex TcNCl4- exclusively, whereas during the Br2 oxidation technetium(VI) intermediates are generated containing mixed Br/dto coordination spheres which can be monitored easily by EPR spectroscopy.
UR - http://www.scopus.com/inward/record.url?scp=4244092975&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)82035-6
DO - 10.1016/S0020-1693(00)82035-6
M3 - Article
AN - SCOPUS:4244092975
SN - 0020-1693
VL - 169
SP - 49
EP - 53
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -