Matrix Laser Fluorescence Spectra of Several Fluorobenzene Radical Cations

V. E. Bondybey; T. A. Miller; J. H. English

doi:10.1021/ja00499a033

Matrix Laser Fluorescence Spectra of Several Fluorobenzene Radical Cations

V. E. Bondybey, T. A. Miller, J. H. English

Alcatel-Lucent

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

26 Zitate (Scopus)

Abstract

Several fluorobenzene radical cations were generated by vacuum UV photolysis of the parent fluorobenzenes in solid Ar matrix, and their laser fluorescence excitation spectra were studied. Their spectra show a well-resolved vibronic structure, which appears to be essentially unperturbed by the solid. Vibrational analysis provides strong evidence for the occurrence of a Jahn-Teiler distortion in the degenerate ²E_1g ground slate of C₆F₆⁺.

Originalsprache	Englisch
Seiten (von - bis)	1248-1253
Seitenumfang	6
Fachzeitschrift	Journal of the American Chemical Society
Jahrgang	101
Ausgabenummer	5
DOIs	https://doi.org/10.1021/ja00499a033
Publikationsstatus	Veröffentlicht - 1 Feb. 1979
Extern publiziert	Ja

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10.1021/ja00499a033

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abstract = "Several fluorobenzene radical cations were generated by vacuum UV photolysis of the parent fluorobenzenes in solid Ar matrix, and their laser fluorescence excitation spectra were studied. Their spectra show a well-resolved vibronic structure, which appears to be essentially unperturbed by the solid. Vibrational analysis provides strong evidence for the occurrence of a Jahn-Teiler distortion in the degenerate 2E1g ground slate of C6F6+.",

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AB - Several fluorobenzene radical cations were generated by vacuum UV photolysis of the parent fluorobenzenes in solid Ar matrix, and their laser fluorescence excitation spectra were studied. Their spectra show a well-resolved vibronic structure, which appears to be essentially unperturbed by the solid. Vibrational analysis provides strong evidence for the occurrence of a Jahn-Teiler distortion in the degenerate 2E1g ground slate of C6F6+.

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Matrix Laser Fluorescence Spectra of Several Fluorobenzene Radical Cations

Abstract

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