TY - JOUR
T1 - Macrotricyclic Borane—Amine Adducts
T2 - The First Uncharged Synthetic Host Compounds Without Lewis Acid Character, for Anionic Guests
AU - Worm, Karin
AU - Schmidtchen, Franz P.
AU - Schier, Annette
AU - Schäfer, Andrea
AU - Hesse, Manfred
PY - 1994/2/18
Y1 - 1994/2/18
N2 - Anions as guests in electroneutral host compounds that have no Lewis acid character—this has been achieved for the first time. The borane–amine adduct 1 functions as host, and examples of guests are Cl−, I−, and CN−. Prerequisite for the supramolecular inclusion of the anions is the exact preorganization of the strong BN dipoles. X(CH2) 6− (Figure Presented.)
AB - Anions as guests in electroneutral host compounds that have no Lewis acid character—this has been achieved for the first time. The borane–amine adduct 1 functions as host, and examples of guests are Cl−, I−, and CN−. Prerequisite for the supramolecular inclusion of the anions is the exact preorganization of the strong BN dipoles. X(CH2) 6− (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33750521101&partnerID=8YFLogxK
U2 - 10.1002/anie.199403271
DO - 10.1002/anie.199403271
M3 - Article
AN - SCOPUS:33750521101
SN - 0570-0833
VL - 33
SP - 327
EP - 329
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 3
ER -