Macrotricyclic Borane—Amine Adducts: The First Uncharged Synthetic Host Compounds Without Lewis Acid Character, for Anionic Guests

Karin Worm, Franz P. Schmidtchen, Annette Schier, Andrea Schäfer, Manfred Hesse

Publikation: Beitrag in FachzeitschriftArtikelBegutachtung

64 Zitate (Scopus)

Abstract

Anions as guests in electroneutral host compounds that have no Lewis acid character—this has been achieved for the first time. The borane–amine adduct 1 functions as host, and examples of guests are Cl, I, and CN. Prerequisite for the supramolecular inclusion of the anions is the exact preorganization of the strong BN dipoles. X(CH2) 6− (Figure Presented.)

OriginalspracheEnglisch
Seiten (von - bis)327-329
Seitenumfang3
FachzeitschriftAngewandte Chemie International Edition in English
Jahrgang33
Ausgabenummer3
DOIs
PublikationsstatusVeröffentlicht - 18 Feb. 1994

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