Isometallocenes. Part 1. Polymethylated isocobaltocenium salts; A general route to [co(C4Me4)(arene)]+

Malcolm R. Cook; Peter Härter; Peter L. Pauson; Ján Šraga

doi:10.1039/DT9870002757

Isometallocenes. Part 1. Polymethylated isocobaltocenium salts; A general route to [co(C₄Me₄)(arene)]⁺

Malcolm R. Cook, Peter Härter, Peter L. Pauson, Ján Šraga

University of Strathclyde

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

37 Zitate (Scopus)

Abstract

The formation of tricarbonyl(tetramethylcyclobutadiene)cobalt hexafluorophosphate and its conversion into the neutral complexes [{Co(CO)₂(C₄Me₄)}₂] and [Co(CO)₂(C₄Me₄)I] are described. Reaction of the latter with arenes in the presence of aluminium chloride provides a general route to the cations [Co(C₄Me₄)(arene)]⁺ of which seven new examples are described. Some carbonyl substitutions of the cation [Co(CO)₃(C₄Me₄)]⁺ are also reported.

Originalsprache	Englisch
Seiten (von - bis)	2757-2760
Seitenumfang	4
Fachzeitschrift	Journal of the Chemical Society. Dalton Transactions
Ausgabenummer	11
DOIs	https://doi.org/10.1039/DT9870002757
Publikationsstatus	Veröffentlicht - 1987
Extern publiziert	Ja

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10.1039/DT9870002757

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abstract = "The formation of tricarbonyl(tetramethylcyclobutadiene)cobalt hexafluorophosphate and its conversion into the neutral complexes [{Co(CO)2(C4Me4)}2] and [Co(CO)2(C4Me4)I] are described. Reaction of the latter with arenes in the presence of aluminium chloride provides a general route to the cations [Co(C4Me4)(arene)]+ of which seven new examples are described. Some carbonyl substitutions of the cation [Co(CO)3(C4Me4)]+ are also reported.",

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year = "1987",

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journal = "Journal of the Chemical Society. Dalton Transactions",

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T1 - Isometallocenes. Part 1. Polymethylated isocobaltocenium salts; A general route to [co(C4Me4)(arene)]+

AU - Cook, Malcolm R.

AU - Härter, Peter

AU - Pauson, Peter L.

AU - Šraga, Ján

PY - 1987

Y1 - 1987

N2 - The formation of tricarbonyl(tetramethylcyclobutadiene)cobalt hexafluorophosphate and its conversion into the neutral complexes [{Co(CO)2(C4Me4)}2] and [Co(CO)2(C4Me4)I] are described. Reaction of the latter with arenes in the presence of aluminium chloride provides a general route to the cations [Co(C4Me4)(arene)]+ of which seven new examples are described. Some carbonyl substitutions of the cation [Co(CO)3(C4Me4)]+ are also reported.

AB - The formation of tricarbonyl(tetramethylcyclobutadiene)cobalt hexafluorophosphate and its conversion into the neutral complexes [{Co(CO)2(C4Me4)}2] and [Co(CO)2(C4Me4)I] are described. Reaction of the latter with arenes in the presence of aluminium chloride provides a general route to the cations [Co(C4Me4)(arene)]+ of which seven new examples are described. Some carbonyl substitutions of the cation [Co(CO)3(C4Me4)]+ are also reported.

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U2 - 10.1039/DT9870002757

DO - 10.1039/DT9870002757

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JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 11