Insights into the in Vitro and in Vivo SAR of Abscisic Acid – Exploring Unprecedented Variations of the Side Chain via Cross-Coupling-Mediated Syntheses

Jens Frackenpohl, Erwin Grill, Guido Bojack, Rachel Baltz, Marco Busch, Jan Dittgen, Jana Franke, Jörg Freigang, Susana Gonzalez, Ines Heinemann, Hendrik Helmke, Martin Hills, Sabine Hohmann, Pascal von Koskull-Döring, Jochen Kleemann, Gudrun Lange, Stefan Lehr, Thomas Müller, Elisabeth Peschel, Fabien PoreeDirk Schmutzler, Arno Schulz, Lothar Willms, Christian Wunschel

Publikation: Beitrag in FachzeitschriftArtikelBegutachtung

19 Zitate (Scopus)

Abstract

Novel analogues of the plant hormone abscisic acid (ABA) were designed and prepared to explore the impact that modifications of its terpenoid side chain have on receptor affinity and in vivo efficacy against drought stress in selected crops. Their efficient and versatile synthesis proceeded via Stille or Sonogashira couplings, shortening the synthetic route significantly. In line with molecular modelling and X-ray crystallography studies novel ABA-derivatives with small alkyl, cycloalkyl or haloalkyl substituents showed strong effects in vitro and in vivo against drought stress in crops, particularly canola and wheat.

OriginalspracheEnglisch
Seiten (von - bis)1403-1415
Seitenumfang13
FachzeitschriftEuropean Journal of Organic Chemistry
Jahrgang2018
Ausgabenummer12
DOIs
PublikationsstatusVeröffentlicht - 29 März 2018

Fingerprint

Untersuchen Sie die Forschungsthemen von „Insights into the in Vitro and in Vivo SAR of Abscisic Acid – Exploring Unprecedented Variations of the Side Chain via Cross-Coupling-Mediated Syntheses“. Zusammen bilden sie einen einzigartigen Fingerprint.

Dieses zitieren