In Situ Surface Reconstruction toward Planar Heterojunction for Efficient and Stable FAPbI3 Quantum Dot Solar Cells

Maoxin Li, Yaqi Bao, Wei Hui, Kun Sun, Lei Gu, Xinxin Kang, Dourong Wang, Baohua Wang, Haoran Deng, Renjun Guo, Zerui Li, Xiongzhuo Jiang, Peter Müller-Buschbaum, Lin Song, Wei Huang

Publikation: Beitrag in FachzeitschriftArtikelBegutachtung

20 Zitate (Scopus)

Abstract

Pure-phase α-FAPbI3 quantum dots (QDs) are the focus of an increasing interest in photovoltaics due to their superior ambient stability, large absorption coefficient, and long charge-carrier lifetime. However, the trap states induced by the ligand-exchange process limit the photovoltaic performances. Here, a simple post treatment using methylamine thiocyanate is developed to reconstruct the FAPbI3-QD film surface, in which a MAPbI3 capping layer with a thickness of 6.2 nm is formed on the film top. This planar perovskite heterojunction leads to a reduced density of trap-states, a decreased band gap, and a facilitated charge carrier transport. As a result, a record high power conversion efficiency (PCE) of 16.23% with negligible hysteresis is achieved for the FAPbI3 QD solar cell, and it retains over 90% of the initial PCE after being stored in ambient environment for 1000 h.

OriginalspracheEnglisch
Aufsatznummer2309890
FachzeitschriftAdvanced Materials
Jahrgang36
Ausgabenummer6
DOIs
PublikationsstatusVeröffentlicht - 8 Feb. 2024

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