Improved stability of solid state light emitting electrochemical cells consisting of ruthenium and iridium complexes

Henk Jan Bolink, Luca Cappelli, Eugenio Coronado, Rubén D. Costa, Michael Graetzel, Md K. Nazeeruddin, Pedro M. Viruela, Enrique Ortí

Publikation: Beitrag in Buch/Bericht/KonferenzbandKonferenzbeitragBegutachtung

1 Zitat (Scopus)

Abstract

Two charged organometallic complexes containing bulky hydrophobic ligands based on ruthenium (II) and iridium (III) were synthesized and their performance in solid state light emitting electrochemical cells is described. The complexes were chosen as due to their large ligands a diminished susceptibility towards the formation of destructive complexes during device operation is expected. The LEC device performances reveal the longest living devices reported so far under dc bias. Quantum chemical calculations confirm that the major effect of the bulky diphenylphenanthroline ligands is of steric origin and not related with changes in the molecular electronic structure of the complexes.

OriginalspracheEnglisch
TitelOrganic Electronics
UntertitelMaterials, Devices and Applications
Herausgeber (Verlag)Materials Research Society
Seiten171-178
Seitenumfang8
ISBN (Print)9781604234176
DOIs
PublikationsstatusVeröffentlicht - 2007
Extern publiziertJa
Veranstaltung2006 MRS Fall Meeting - Boston, MA, USA/Vereinigte Staaten
Dauer: 27 Nov. 20061 Dez. 2006

Publikationsreihe

NameMaterials Research Society Symposium Proceedings
Band965
ISSN (Print)0272-9172

Konferenz

Konferenz2006 MRS Fall Meeting
Land/GebietUSA/Vereinigte Staaten
OrtBoston, MA
Zeitraum27/11/061/12/06

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