Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

Ayyamperumal Sakthivel; Filipe M. Pedro; Anthony S.T. Chiang; Fritz E. Kühn

doi:10.1039/b611550k

Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

Ayyamperumal Sakthivel, Filipe M. Pedro, Anthony S.T. Chiang, Fritz E. Kühn

Professur für Molekulare Katalyse

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

11 Zitate (Scopus)

Abstract

Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N₂ adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.

Originalsprache	Englisch
Seiten (von - bis)	320-326
Seitenumfang	7
Fachzeitschrift	Dalton Transactions
Ausgabenummer	3
DOIs	https://doi.org/10.1039/b611550k
Publikationsstatus	Veröffentlicht - 2007

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abstract = "Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.",

author = "Ayyamperumal Sakthivel and Pedro, {Filipe M.} and Chiang, {Anthony S.T.} and K{\"u}hn, {Fritz E.}",

year = "2007",

doi = "10.1039/b611550k",

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T1 - Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

AU - Sakthivel, Ayyamperumal

AU - Pedro, Filipe M.

AU - Chiang, Anthony S.T.

AU - Kühn, Fritz E.

PY - 2007

Y1 - 2007

N2 - Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.

AB - Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.

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U2 - 10.1039/b611550k

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ER -

Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

Abstract

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