Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization

Ming Fang Cai; Terry A. Miller; V. E. Bondybey

doi:10.1016/0009-2614(89)87373-7

Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization

Ming Fang Cai, Terry A. Miller, V. E. Bondybey

Ohio State University

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

21 Zitate (Scopus)

Abstract

Reactive Ba atoms are produced from a Ba rod by YAG laser vaporization in the throat of a seeded He supersonic jet expansion. As the expansion proceeds, the Ba atoms react with the seed gas, benzyl chloride. The reaction products, BaCl and benzyl radical, are observed substantially cooled downstream via laser-induced fluorescence.

Originalsprache	Englisch
Seiten (von - bis)	475-479
Seitenumfang	5
Fachzeitschrift	Chemical Physics Letters
Jahrgang	158
Ausgabenummer	6
DOIs	https://doi.org/10.1016/0009-2614(89)87373-7
Publikationsstatus	Veröffentlicht - 23 Juni 1989
Extern publiziert	Ja

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10.1016/0009-2614(89)87373-7

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title = "Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization",

abstract = "Reactive Ba atoms are produced from a Ba rod by YAG laser vaporization in the throat of a seeded He supersonic jet expansion. As the expansion proceeds, the Ba atoms react with the seed gas, benzyl chloride. The reaction products, BaCl and benzyl radical, are observed substantially cooled downstream via laser-induced fluorescence.",

author = "Cai, {Ming Fang} and Miller, {Terry A.} and Bondybey, {V. E.}",

note = "Funding Information: The authors gratefullya cknowledget he support of the National ScienceF oundation in this work through grants CHE8803169 (MFC and VEB) and CHE8507537 (TAM).",

year = "1989",

month = jun,

day = "23",

doi = "10.1016/0009-2614(89)87373-7",

language = "English",

volume = "158",

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journal = "Chemical Physics Letters",

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T1 - Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization

AU - Cai, Ming Fang

AU - Miller, Terry A.

AU - Bondybey, V. E.

N1 - Funding Information: The authors gratefullya cknowledget he support of the National ScienceF oundation in this work through grants CHE8803169 (MFC and VEB) and CHE8507537 (TAM).

PY - 1989/6/23

Y1 - 1989/6/23

N2 - Reactive Ba atoms are produced from a Ba rod by YAG laser vaporization in the throat of a seeded He supersonic jet expansion. As the expansion proceeds, the Ba atoms react with the seed gas, benzyl chloride. The reaction products, BaCl and benzyl radical, are observed substantially cooled downstream via laser-induced fluorescence.

AB - Reactive Ba atoms are produced from a Ba rod by YAG laser vaporization in the throat of a seeded He supersonic jet expansion. As the expansion proceeds, the Ba atoms react with the seed gas, benzyl chloride. The reaction products, BaCl and benzyl radical, are observed substantially cooled downstream via laser-induced fluorescence.

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U2 - 10.1016/0009-2614(89)87373-7

DO - 10.1016/0009-2614(89)87373-7

M3 - Article

AN - SCOPUS:4243447226

SN - 0009-2614

VL - 158

SP - 475

EP - 479

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 6

ER -

Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization

Abstract

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