Fulvenylsubstituierte Cp-liganden. IV. Ein stabiles heterodinukleares donor/ akzeptor-System mit 6-Pentafulvenylcyclopentadienyl-Brücke

Peter Härter; Julia David

doi:10.1016/0022-328X(93)86093-W

Fulvenylsubstituierte Cp-liganden. IV. Ein stabiles heterodinukleares donor/ akzeptor-System mit 6-Pentafulvenylcyclopentadienyl-Brücke

Peter Härter, Julia David

Natural Sciences

Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

Abstract

The synthesis and spectroscopic behaviour of (CO)₃Cr(C₅H₄CH-C₅H₄)FeC₅H₅ is described. The compound shows a bathochromic shift in the UV/vis-spectra of 20 nm upon changing the solvent from n-hexane to THF. The NMR spectra suggest that there is no internal rotational motion in the molecule at room temperature.

Originalsprache	Englisch
Seiten (von - bis)	C12-C14
Fachzeitschrift	Journal of Organometallic Chemistry
Jahrgang	459
Ausgabenummer	1-2
DOIs	https://doi.org/10.1016/0022-328X(93)86093-W
Publikationsstatus	Veröffentlicht - 19 Okt. 1993

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10.1016/0022-328X(93)86093-W

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abstract = "The synthesis and spectroscopic behaviour of (CO)3Cr(C5H4CH-C5H4)FeC5H5 is described. The compound shows a bathochromic shift in the UV/vis-spectra of 20 nm upon changing the solvent from n-hexane to THF. The NMR spectra suggest that there is no internal rotational motion in the molecule at room temperature.",

author = "Peter H{\"a}rter and Julia David",

year = "1993",

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doi = "10.1016/0022-328X(93)86093-W",

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AU - David, Julia

PY - 1993/10/19

Y1 - 1993/10/19

N2 - The synthesis and spectroscopic behaviour of (CO)3Cr(C5H4CH-C5H4)FeC5H5 is described. The compound shows a bathochromic shift in the UV/vis-spectra of 20 nm upon changing the solvent from n-hexane to THF. The NMR spectra suggest that there is no internal rotational motion in the molecule at room temperature.

AB - The synthesis and spectroscopic behaviour of (CO)3Cr(C5H4CH-C5H4)FeC5H5 is described. The compound shows a bathochromic shift in the UV/vis-spectra of 20 nm upon changing the solvent from n-hexane to THF. The NMR spectra suggest that there is no internal rotational motion in the molecule at room temperature.

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Fulvenylsubstituierte Cp-liganden. IV. Ein stabiles heterodinukleares donor/ akzeptor-System mit 6-Pentafulvenylcyclopentadienyl-Brücke

Abstract

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