Enantioselective, intermolecular [2+2] photocycloaddition reactions of 3-acetoxyquinolone: total synthesis of (−)-pinolinone

Florian Mayr; Christian Wiegand; Thorsten Bach

doi:10.1039/c3cc49469a

Enantioselective, intermolecular [2+2] photocycloaddition reactions of 3-acetoxyquinolone: total synthesis of (−)-pinolinone

Florian Mayr, Christian Wiegand, Thorsten Bach

Lehrstuhl für Organische Chemie I

Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

23 Zitate (Scopus)

Abstract

The natural product (−)-pinolinone was synthesised via a concise route (six steps, 17% overall yield) from 3-acetoxyquinolone, employing an enantioselective intermolecular [2+2] photocycloaddition as the key step.

Originalsprache	Englisch
Seiten (von - bis)	3353-3355
Seitenumfang	3
Fachzeitschrift	Chemical Communications
Jahrgang	50
Ausgabenummer	25
DOIs	https://doi.org/10.1039/c3cc49469a
Publikationsstatus	Veröffentlicht - 27 Feb. 2014

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10.1039/c3cc49469a

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title = "Enantioselective, intermolecular [2+2] photocycloaddition reactions of 3-acetoxyquinolone: total synthesis of (−)-pinolinone",

abstract = "The natural product (−)-pinolinone was synthesised via a concise route (six steps, 17% overall yield) from 3-acetoxyquinolone, employing an enantioselective intermolecular [2+2] photocycloaddition as the key step.",

author = "Florian Mayr and Christian Wiegand and Thorsten Bach",

year = "2014",

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day = "27",

doi = "10.1039/c3cc49469a",

language = "English",

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AU - Mayr, Florian

AU - Wiegand, Christian

AU - Bach, Thorsten

PY - 2014/2/27

Y1 - 2014/2/27

N2 - The natural product (−)-pinolinone was synthesised via a concise route (six steps, 17% overall yield) from 3-acetoxyquinolone, employing an enantioselective intermolecular [2+2] photocycloaddition as the key step.

AB - The natural product (−)-pinolinone was synthesised via a concise route (six steps, 17% overall yield) from 3-acetoxyquinolone, employing an enantioselective intermolecular [2+2] photocycloaddition as the key step.

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U2 - 10.1039/c3cc49469a

DO - 10.1039/c3cc49469a

M3 - Article

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Enantioselective, intermolecular [2+2] photocycloaddition reactions of 3-acetoxyquinolone: total synthesis of (−)-pinolinone

Abstract

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