Elaboration of a Highly Porous RuII,II Analogue of HKUST-1

Wenhua Zhang; Kerstin Freitag; Suttipong Wannapaiboon; Christian Schneider; Konstantin Epp; Gregor Kieslich; Roland A. Fischer

doi:10.1021/acs.inorgchem.6b02038

Elaboration of a Highly Porous Ru^II,II Analogue of HKUST-1

Wenhua Zhang, Kerstin Freitag, Suttipong Wannapaiboon, Christian Schneider, Konstantin Epp, Gregor Kieslich, Roland A. Fischer

Lehrstuhl für Anorganische und Metallorganische Chemie

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

17 Zitate (Scopus)

Abstract

When the dinuclear Ru^II,II precursor [Ru₂(OOCCH₃)₄] is employed under redox-inert conditions, a Ru^II,II analogue of HKUST-1 was successfully prepared and characterized as a phase-pure microcrystalline powder. X-ray absorption near-edge spectroscopy confirms the oxidation state of the Ru centers of the paddle-wheel nodes in the framework. The porosity of 1371 m²/mmol of Ru^II,II-HKUST-1 exceeds that of the parent compound HKUST1 (1049 m²/ mmol).

Originalsprache	Englisch
Seiten (von - bis)	12492-12495
Seitenumfang	4
Fachzeitschrift	Inorganic Chemistry
Jahrgang	55
Ausgabenummer	24
DOIs	https://doi.org/10.1021/acs.inorgchem.6b02038
Publikationsstatus	Veröffentlicht - 19 Dez. 2016

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10.1021/acs.inorgchem.6b02038

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abstract = "When the dinuclear RuII,II precursor [Ru2(OOCCH3)4] is employed under redox-inert conditions, a RuII,II analogue of HKUST-1 was successfully prepared and characterized as a phase-pure microcrystalline powder. X-ray absorption near-edge spectroscopy confirms the oxidation state of the Ru centers of the paddle-wheel nodes in the framework. The porosity of 1371 m2/mmol of RuII,II-HKUST-1 exceeds that of the parent compound HKUST1 (1049 m2/ mmol).",

author = "Wenhua Zhang and Kerstin Freitag and Suttipong Wannapaiboon and Christian Schneider and Konstantin Epp and Gregor Kieslich and Fischer, {Roland A.}",

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T1 - Elaboration of a Highly Porous RuII,II Analogue of HKUST-1

AU - Zhang, Wenhua

AU - Freitag, Kerstin

AU - Wannapaiboon, Suttipong

AU - Schneider, Christian

AU - Epp, Konstantin

AU - Kieslich, Gregor

AU - Fischer, Roland A.

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N2 - When the dinuclear RuII,II precursor [Ru2(OOCCH3)4] is employed under redox-inert conditions, a RuII,II analogue of HKUST-1 was successfully prepared and characterized as a phase-pure microcrystalline powder. X-ray absorption near-edge spectroscopy confirms the oxidation state of the Ru centers of the paddle-wheel nodes in the framework. The porosity of 1371 m2/mmol of RuII,II-HKUST-1 exceeds that of the parent compound HKUST1 (1049 m2/ mmol).

AB - When the dinuclear RuII,II precursor [Ru2(OOCCH3)4] is employed under redox-inert conditions, a RuII,II analogue of HKUST-1 was successfully prepared and characterized as a phase-pure microcrystalline powder. X-ray absorption near-edge spectroscopy confirms the oxidation state of the Ru centers of the paddle-wheel nodes in the framework. The porosity of 1371 m2/mmol of RuII,II-HKUST-1 exceeds that of the parent compound HKUST1 (1049 m2/ mmol).

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