DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds

Richard Holzner; Dominik Reiter; Philipp Frisch; Shigeyoshi Inoue

doi:10.1039/c9ra10628f

DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds

Richard Holzner, Dominik Reiter, Philipp Frisch, Shigeyoshi Inoue

Professur für Siliciumchemie

Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

20 Zitate (Scopus)

Abstract

DMAP-stabilized silylenes 1a-c are obtained from the reductive debromination of the corresponding dibromosilanes in the presence of DMAP. Their distinctly different thermal isomerization reactions via C-H bond activation, dearomative ring expansion and silyl migration are discussed. Furthermore, complexes 1 dissociate at elevated temperatures, providing the corresponding free silylenes in situ, which are even capable of single-site activation of H₂.

Originalsprache	Englisch
Seiten (von - bis)	3402-3406
Seitenumfang	5
Fachzeitschrift	RSC Advances
Jahrgang	10
Ausgabenummer	6
DOIs	https://doi.org/10.1039/c9ra10628f
Publikationsstatus	Veröffentlicht - 2020

Zugriff auf Dokument

10.1039/c9ra10628f

Andere Dateien und Links

Verknüpfung zur Publikation in Scopus

Dieses zitieren

@article{6d90f8d75fa943b191a5855ed0fae1e8,

title = "DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds",

abstract = "DMAP-stabilized silylenes 1a-c are obtained from the reductive debromination of the corresponding dibromosilanes in the presence of DMAP. Their distinctly different thermal isomerization reactions via C-H bond activation, dearomative ring expansion and silyl migration are discussed. Furthermore, complexes 1 dissociate at elevated temperatures, providing the corresponding free silylenes in situ, which are even capable of single-site activation of H2.",

author = "Richard Holzner and Dominik Reiter and Philipp Frisch and Shigeyoshi Inoue",

note = "Publisher Copyright: {\textcopyright} 2020 The Royal Society of Chemistry.",

year = "2020",

doi = "10.1039/c9ra10628f",

language = "English",

volume = "10",

pages = "3402--3406",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "6",

}

TY - JOUR

T1 - DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds

AU - Holzner, Richard

AU - Reiter, Dominik

AU - Frisch, Philipp

AU - Inoue, Shigeyoshi

PY - 2020

Y1 - 2020

N2 - DMAP-stabilized silylenes 1a-c are obtained from the reductive debromination of the corresponding dibromosilanes in the presence of DMAP. Their distinctly different thermal isomerization reactions via C-H bond activation, dearomative ring expansion and silyl migration are discussed. Furthermore, complexes 1 dissociate at elevated temperatures, providing the corresponding free silylenes in situ, which are even capable of single-site activation of H2.

AB - DMAP-stabilized silylenes 1a-c are obtained from the reductive debromination of the corresponding dibromosilanes in the presence of DMAP. Their distinctly different thermal isomerization reactions via C-H bond activation, dearomative ring expansion and silyl migration are discussed. Furthermore, complexes 1 dissociate at elevated temperatures, providing the corresponding free silylenes in situ, which are even capable of single-site activation of H2.

UR - http://www.scopus.com/inward/record.url?scp=85078528965&partnerID=8YFLogxK

U2 - 10.1039/c9ra10628f

DO - 10.1039/c9ra10628f

M3 - Article

AN - SCOPUS:85078528965

SN - 2046-2069

VL - 10

SP - 3402

EP - 3406

JO - RSC Advances

JF - RSC Advances

IS - 6

ER -

DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds

Abstract

Zugriff auf Dokument

Andere Dateien und Links

Fingerprint

Dieses zitieren