Dissociation energy and excited-state properties of diatomic Sn2

K. Pak; M. F. Cai; T. P. Dzugan; V. E. Bondybey

doi:10.1039/DC9888600153

Dissociation energy and excited-state properties of diatomic Sn₂

K. Pak, M. F. Cai, T. P. Dzugan, V. E. Bondybey

Lehrstuhl für Physikalische Chemie

Ohio State University

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

32 Zitate (Scopus)

Abstract

Laser vaporization of metallic tin is used to generate Sn₂ molecules in effusive and supersonic expansions. Laser-induced fluorescence studies using isotopic samples of ¹²⁰Sn established the correct vibrational numbering in the excited F 0_u⁺ and determined the Sn₂ molecular constants. From the convergence limit of the upper state the Sn₂ dissociation energy was determined to be 15 330 ± 25 cm^-1, in good agreement with recent ab initio theoretical predictions.

Originalsprache	Englisch
Seiten (von - bis)	153-162
Seitenumfang	10
Fachzeitschrift	Faraday Discussions of the Chemical Society
Jahrgang	86
DOIs	https://doi.org/10.1039/DC9888600153
Publikationsstatus	Veröffentlicht - 1988

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title = "Dissociation energy and excited-state properties of diatomic Sn2",

abstract = "Laser vaporization of metallic tin is used to generate Sn2 molecules in effusive and supersonic expansions. Laser-induced fluorescence studies using isotopic samples of 120Sn established the correct vibrational numbering in the excited F 0u+ and determined the Sn2 molecular constants. From the convergence limit of the upper state the Sn2 dissociation energy was determined to be 15 330 ± 25 cm-1, in good agreement with recent ab initio theoretical predictions.",

author = "K. Pak and Cai, {M. F.} and Dzugan, {T. P.} and Bondybey, {V. E.}",

year = "1988",

doi = "10.1039/DC9888600153",

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AU - Pak, K.

AU - Cai, M. F.

AU - Dzugan, T. P.

AU - Bondybey, V. E.

PY - 1988

Y1 - 1988

N2 - Laser vaporization of metallic tin is used to generate Sn2 molecules in effusive and supersonic expansions. Laser-induced fluorescence studies using isotopic samples of 120Sn established the correct vibrational numbering in the excited F 0u+ and determined the Sn2 molecular constants. From the convergence limit of the upper state the Sn2 dissociation energy was determined to be 15 330 ± 25 cm-1, in good agreement with recent ab initio theoretical predictions.

AB - Laser vaporization of metallic tin is used to generate Sn2 molecules in effusive and supersonic expansions. Laser-induced fluorescence studies using isotopic samples of 120Sn established the correct vibrational numbering in the excited F 0u+ and determined the Sn2 molecular constants. From the convergence limit of the upper state the Sn2 dissociation energy was determined to be 15 330 ± 25 cm-1, in good agreement with recent ab initio theoretical predictions.

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JO - Faraday Discussions of the Chemical Society

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