Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

Saurav Bhattacharya; Wassim W. Ayass; Dereje H. Taffa; Andreas Schneemann; A. Lisa Semrau; Suttipong Wannapaiboon; Philipp J. Altmann; Alexander Pöthig; Talha Nisar; Torsten Balster; Nicholas C. Burtch; Veit Wagner; Roland A. Fischer; Michael Wark; Ulrich Kortz

doi:10.1021/jacs.8b13397

Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

Saurav Bhattacharya, Wassim W. Ayass, Dereje H. Taffa, Andreas Schneemann, A. Lisa Semrau, Suttipong Wannapaiboon, Philipp J. Altmann, Alexander Pöthig, Talha Nisar, Torsten Balster, Nicholas C. Burtch, Veit Wagner, Roland A. Fischer, Michael Wark, Ulrich Kortz

Lehrstuhl für Anorganische und Metallorganische Chemie

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

44 Zitate (Scopus)

Abstract

Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd₁₃O₈(AsO₄)₈H₆]^8- decorated by four Ba²⁺ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.

Originalsprache	Englisch
Seiten (von - bis)	3385-3389
Seitenumfang	5
Fachzeitschrift	Journal of the American Chemical Society
Jahrgang	141
Ausgabenummer	8
DOIs	https://doi.org/10.1021/jacs.8b13397
Publikationsstatus	Veröffentlicht - 27 Feb. 2019

Zugriff auf Dokument

10.1021/jacs.8b13397

Andere Dateien und Links

Verknüpfung zur Publikation in Scopus

Dieses zitieren

Bhattacharya, S., Ayass, W. W., Taffa, D. H., Schneemann, A., Semrau, A. L., Wannapaiboon, S., Altmann, P. J., Pöthig, A., Nisar, T., Balster, T., Burtch, N. C., Wagner, V., Fischer, R. A., Wark, M., & Kortz, U. (2019). Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks. Journal of the American Chemical Society, 141(8), 3385-3389. https://doi.org/10.1021/jacs.8b13397

@article{6f95897138d1495388203fa762116804,

title = "Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks",

abstract = "Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)8H6]8- decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.",

author = "Saurav Bhattacharya and Ayass, {Wassim W.} and Taffa, {Dereje H.} and Andreas Schneemann and Semrau, {A. Lisa} and Suttipong Wannapaiboon and Altmann, {Philipp J.} and Alexander P{\"o}thig and Talha Nisar and Torsten Balster and Burtch, {Nicholas C.} and Veit Wagner and Fischer, {Roland A.} and Michael Wark and Ulrich Kortz",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = feb,

day = "27",

doi = "10.1021/jacs.8b13397",

language = "English",

volume = "141",

pages = "3385--3389",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

AU - Bhattacharya, Saurav

AU - Ayass, Wassim W.

AU - Taffa, Dereje H.

AU - Schneemann, Andreas

AU - Semrau, A. Lisa

AU - Wannapaiboon, Suttipong

AU - Altmann, Philipp J.

AU - Pöthig, Alexander

AU - Nisar, Talha

AU - Balster, Torsten

AU - Burtch, Nicholas C.

AU - Wagner, Veit

AU - Fischer, Roland A.

AU - Wark, Michael

AU - Kortz, Ulrich

PY - 2019/2/27

Y1 - 2019/2/27

N2 - Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)8H6]8- decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.

AB - Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)8H6]8- decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.

UR - http://www.scopus.com/inward/record.url?scp=85062258045&partnerID=8YFLogxK

U2 - 10.1021/jacs.8b13397

DO - 10.1021/jacs.8b13397

M3 - Article

C2 - 30712351

AN - SCOPUS:85062258045

SN - 0002-7863

VL - 141

SP - 3385

EP - 3389

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 8

ER -

Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

Abstract

Zugriff auf Dokument

Andere Dateien und Links

Fingerprint

Dieses zitieren