Direct Integration of Strained-Pt Catalysts into Proton-Exchange-Membrane Fuel Cells with Atomic Layer Deposition

Shicheng Xu; Zhaoxuan Wang; Sam Dull; Yunzhi Liu; Dong Un Lee; Juan S. Lezama Pacheco; Marat Orazov; Per Erik Vullum; Anup Lal Dadlani; Olga Vinogradova; Peter Schindler; Qizhan Tam; Thomas D. Schladt; Jonathan E. Mueller; Sebastian Kirsch; Gerold Huebner; Drew Higgins; Jan Torgersen; Venkatasubramanian Viswanathan; Thomas Francisco Jaramillo; Fritz B. Prinz

doi:10.1002/adma.202007885

Direct Integration of Strained-Pt Catalysts into Proton-Exchange-Membrane Fuel Cells with Atomic Layer Deposition

Shicheng Xu, Zhaoxuan Wang, Sam Dull, Yunzhi Liu, Dong Un Lee, Juan S. Lezama Pacheco, Marat Orazov, Per Erik Vullum, Anup Lal Dadlani, Olga Vinogradova, Peter Schindler, Qizhan Tam, Thomas D. Schladt, Jonathan E. Mueller, Sebastian Kirsch, Gerold Huebner, Drew Higgins, Jan Torgersen, Venkatasubramanian Viswanathan, Thomas Francisco JaramilloFritz B. Prinz

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

15 Zitate (Scopus)

Abstract

The design and fabrication of lattice-strained platinum catalysts achieved by removing a soluble core from a platinum shell synthesized via atomic layer deposition, is reported. The remarkable catalytic performance for the oxygen reduction reaction (ORR), measured in both half-cell and full-cell configurations, is attributed to the observed lattice strain. By further optimizing the nanoparticle geometry and ionomer/carbon interactions, mass activity close to 0.8 A mg_Pt⁻¹ @0.9 V iR-free is achievable in the membrane electrode assembly. Nevertheless, active catalysts with high ORR activity do not necessarily lead to high performance in the high-current-density (HCD) region. More attention shall be directed toward HCD performance for enabling high-power-density hydrogen fuel cells.

Originalsprache	Englisch
Aufsatznummer	2007885
Fachzeitschrift	Advanced Materials
Jahrgang	33
Ausgabenummer	30
DOIs	https://doi.org/10.1002/adma.202007885
Publikationsstatus	Veröffentlicht - 28 Juli 2021
Extern publiziert	Ja

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10.1002/adma.202007885

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Xu, S., Wang, Z., Dull, S., Liu, Y., Lee, D. U., Lezama Pacheco, J. S., Orazov, M., Vullum, P. E., Dadlani, A. L., Vinogradova, O., Schindler, P., Tam, Q., Schladt, T. D., Mueller, J. E., Kirsch, S., Huebner, G., Higgins, D., Torgersen, J., Viswanathan, V., ... Prinz, F. B. (2021). Direct Integration of Strained-Pt Catalysts into Proton-Exchange-Membrane Fuel Cells with Atomic Layer Deposition. Advanced Materials, 33(30), Artikel 2007885. https://doi.org/10.1002/adma.202007885

@article{bf244fe98b3e4d738aaa96399e0628a3,

title = "Direct Integration of Strained-Pt Catalysts into Proton-Exchange-Membrane Fuel Cells with Atomic Layer Deposition",

abstract = "The design and fabrication of lattice-strained platinum catalysts achieved by removing a soluble core from a platinum shell synthesized via atomic layer deposition, is reported. The remarkable catalytic performance for the oxygen reduction reaction (ORR), measured in both half-cell and full-cell configurations, is attributed to the observed lattice strain. By further optimizing the nanoparticle geometry and ionomer/carbon interactions, mass activity close to 0.8 A mgPt−1 @0.9 V iR-free is achievable in the membrane electrode assembly. Nevertheless, active catalysts with high ORR activity do not necessarily lead to high performance in the high-current-density (HCD) region. More attention shall be directed toward HCD performance for enabling high-power-density hydrogen fuel cells.",

keywords = "fuel cells, lattice strain, membrane electrode assembly, oxygen reduction reaction, rotating disk electrodes",

author = "Shicheng Xu and Zhaoxuan Wang and Sam Dull and Yunzhi Liu and Lee, {Dong Un} and {Lezama Pacheco}, {Juan S.} and Marat Orazov and Vullum, {Per Erik} and Dadlani, {Anup Lal} and Olga Vinogradova and Peter Schindler and Qizhan Tam and Schladt, {Thomas D.} and Mueller, {Jonathan E.} and Sebastian Kirsch and Gerold Huebner and Drew Higgins and Jan Torgersen and Venkatasubramanian Viswanathan and Jaramillo, {Thomas Francisco} and Prinz, {Fritz B.}",

note = "Publisher Copyright: {\textcopyright} 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH",

year = "2021",

month = jul,

day = "28",

doi = "10.1002/adma.202007885",

language = "English",

volume = "33",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-Blackwell",

number = "30",

}

Xu, S, Wang, Z, Dull, S, Liu, Y, Lee, DU, Lezama Pacheco, JS, Orazov, M, Vullum, PE, Dadlani, AL, Vinogradova, O, Schindler, P, Tam, Q, Schladt, TD, Mueller, JE, Kirsch, S, Huebner, G, Higgins, D, Torgersen, J, Viswanathan, V, Jaramillo, TF & Prinz, FB 2021, 'Direct Integration of Strained-Pt Catalysts into Proton-Exchange-Membrane Fuel Cells with Atomic Layer Deposition', Advanced Materials, Jg. 33, Nr. 30, 2007885. https://doi.org/10.1002/adma.202007885

TY - JOUR

T1 - Direct Integration of Strained-Pt Catalysts into Proton-Exchange-Membrane Fuel Cells with Atomic Layer Deposition

AU - Xu, Shicheng

AU - Wang, Zhaoxuan

AU - Dull, Sam

AU - Liu, Yunzhi

AU - Lee, Dong Un

AU - Lezama Pacheco, Juan S.

AU - Orazov, Marat

AU - Vullum, Per Erik

AU - Dadlani, Anup Lal

AU - Vinogradova, Olga

AU - Schindler, Peter

AU - Tam, Qizhan

AU - Schladt, Thomas D.

AU - Mueller, Jonathan E.

AU - Kirsch, Sebastian

AU - Huebner, Gerold

AU - Higgins, Drew

AU - Torgersen, Jan

AU - Viswanathan, Venkatasubramanian

AU - Jaramillo, Thomas Francisco

AU - Prinz, Fritz B.

PY - 2021/7/28

Y1 - 2021/7/28

N2 - The design and fabrication of lattice-strained platinum catalysts achieved by removing a soluble core from a platinum shell synthesized via atomic layer deposition, is reported. The remarkable catalytic performance for the oxygen reduction reaction (ORR), measured in both half-cell and full-cell configurations, is attributed to the observed lattice strain. By further optimizing the nanoparticle geometry and ionomer/carbon interactions, mass activity close to 0.8 A mgPt−1 @0.9 V iR-free is achievable in the membrane electrode assembly. Nevertheless, active catalysts with high ORR activity do not necessarily lead to high performance in the high-current-density (HCD) region. More attention shall be directed toward HCD performance for enabling high-power-density hydrogen fuel cells.

AB - The design and fabrication of lattice-strained platinum catalysts achieved by removing a soluble core from a platinum shell synthesized via atomic layer deposition, is reported. The remarkable catalytic performance for the oxygen reduction reaction (ORR), measured in both half-cell and full-cell configurations, is attributed to the observed lattice strain. By further optimizing the nanoparticle geometry and ionomer/carbon interactions, mass activity close to 0.8 A mgPt−1 @0.9 V iR-free is achievable in the membrane electrode assembly. Nevertheless, active catalysts with high ORR activity do not necessarily lead to high performance in the high-current-density (HCD) region. More attention shall be directed toward HCD performance for enabling high-power-density hydrogen fuel cells.

KW - fuel cells

KW - lattice strain

KW - membrane electrode assembly

KW - oxygen reduction reaction

KW - rotating disk electrodes

UR - http://www.scopus.com/inward/record.url?scp=85107412679&partnerID=8YFLogxK

U2 - 10.1002/adma.202007885

DO - 10.1002/adma.202007885

M3 - Article

C2 - 34110653

AN - SCOPUS:85107412679

SN - 0935-9648

VL - 33

JO - Advanced Materials

JF - Advanced Materials

IS - 30

M1 - 2007885

ER -

Direct Integration of Strained-Pt Catalysts into Proton-Exchange-Membrane Fuel Cells with Atomic Layer Deposition

Abstract

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