Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2

S. Kissling; M. W. Lehenmeier; P. T. Altenbuchner; A. Kronast; M. Reiter; P. Deglmann; U. B. Seemann; B. Rieger

doi:10.1039/c5cc00784d

Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO₂

S. Kissling, M. W. Lehenmeier, P. T. Altenbuchner, A. Kronast, M. Reiter, P. Deglmann, U. B. Seemann, B. Rieger

Wacker-Lehrstuhl für Makromolekulare Chemie

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

138 Zitate (Scopus)

Abstract

A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155 000 h^-1. These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO₂.

Originalsprache	Englisch
Seiten (von - bis)	4579-4582
Seitenumfang	4
Fachzeitschrift	Chemical Communications
Jahrgang	51
Ausgabenummer	22
DOIs	https://doi.org/10.1039/c5cc00784d
Publikationsstatus	Veröffentlicht - 18 März 2015

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10.1039/c5cc00784d

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abstract = "A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155 000 h-1. These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.",

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AU - Lehenmeier, M. W.

AU - Altenbuchner, P. T.

AU - Kronast, A.

AU - Reiter, M.

AU - Deglmann, P.

AU - Seemann, U. B.

AU - Rieger, B.

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AB - A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155 000 h-1. These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.

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