TY - JOUR
T1 - Differential column measurements using compact solar-tracking spectrometers
AU - Chen, Jia
AU - Viatte, Camille
AU - Hedelius, Jacob K.
AU - Jones, Taylor
AU - Franklin, Jonathan E.
AU - Parker, Harrison
AU - Gottlieb, Elaine W.
AU - Wennberg, Paul O.
AU - Dubey, Manvendra K.
AU - Wofsy, Steven C.
N1 - Publisher Copyright:
© 2016 Author(s).
PY - 2016/7/12
Y1 - 2016/7/12
N2 - We demonstrate the use of compact solar-tracking Fourier transform spectrometers (Bruker EM27/SUN) for differential measurements of the column-averaged dry-air mole fractions of CH4 and CO2 within urban areas. Using Allan variance analysis, we show that the differential column measurement has a precision of 0.01% for XCO2 and XCH4 with an optimum integration time of 10 min, corresponding to Allan deviations of 0.04 ppm and 0.2 ppb, respectively. The sensor system is very stable over time and after relocation across the continent.We report tests of the differential column measurement, and its sensitivity to emission sources, by measuring the downwind-minus-upwind column difference δXCH4 across dairy farms in the Chino area, California, and using the data to verify emissions reported in the literature. Ratios of spatial column differences δXCH4=δXCO2 were observed across Pasadena within the Los Angeles basin, indicating values consistent with regional emission ratios from the literature. Our precise, rapid measurements allow us to determine significant short-term variations (5-10 min) of XCO2 and XCH4 and to show that they represent atmospheric phenomena. Overall, this study helps establish a range of new applications for compact solar-viewing Fourier transform spectrometers. By accurately measuring the small differences in integrated column amounts across local and regional sources, we directly observe the mass loading of the atmosphere due to the influence of emissions in the intervening locale. The inference of the source strength is much more direct than inversion modeling using only surface concentrations and less subject to errors associated with small-scale transport phenomena.
AB - We demonstrate the use of compact solar-tracking Fourier transform spectrometers (Bruker EM27/SUN) for differential measurements of the column-averaged dry-air mole fractions of CH4 and CO2 within urban areas. Using Allan variance analysis, we show that the differential column measurement has a precision of 0.01% for XCO2 and XCH4 with an optimum integration time of 10 min, corresponding to Allan deviations of 0.04 ppm and 0.2 ppb, respectively. The sensor system is very stable over time and after relocation across the continent.We report tests of the differential column measurement, and its sensitivity to emission sources, by measuring the downwind-minus-upwind column difference δXCH4 across dairy farms in the Chino area, California, and using the data to verify emissions reported in the literature. Ratios of spatial column differences δXCH4=δXCO2 were observed across Pasadena within the Los Angeles basin, indicating values consistent with regional emission ratios from the literature. Our precise, rapid measurements allow us to determine significant short-term variations (5-10 min) of XCO2 and XCH4 and to show that they represent atmospheric phenomena. Overall, this study helps establish a range of new applications for compact solar-viewing Fourier transform spectrometers. By accurately measuring the small differences in integrated column amounts across local and regional sources, we directly observe the mass loading of the atmosphere due to the influence of emissions in the intervening locale. The inference of the source strength is much more direct than inversion modeling using only surface concentrations and less subject to errors associated with small-scale transport phenomena.
UR - http://www.scopus.com/inward/record.url?scp=84978496127&partnerID=8YFLogxK
U2 - 10.5194/acp-16-8479-2016
DO - 10.5194/acp-16-8479-2016
M3 - Article
AN - SCOPUS:84978496127
SN - 1680-7316
VL - 16
SP - 8479
EP - 8498
JO - Atmospheric Chemistry and Physics
JF - Atmospheric Chemistry and Physics
IS - 13
ER -