Coinage metal complexes of NHC-stabilized silyliumylidene ions

Philipp Frisch; Shigeyoshi Inoue

doi:10.1039/c8cc07754a

Coinage metal complexes of NHC-stabilized silyliumylidene ions

Philipp Frisch, Shigeyoshi Inoue

Professur für Siliciumchemie

Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

14 Zitate (Scopus)

Abstract

The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me₂S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.

Originalsprache	Englisch
Seiten (von - bis)	13658-13661
Seitenumfang	4
Fachzeitschrift	Chemical Communications
Jahrgang	54
Ausgabenummer	97
DOIs	https://doi.org/10.1039/c8cc07754a
Publikationsstatus	Veröffentlicht - 2018

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abstract = "The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.",

author = "Philipp Frisch and Shigeyoshi Inoue",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8cc07754a",

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AU - Inoue, Shigeyoshi

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AB - The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.

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Coinage metal complexes of NHC-stabilized silyliumylidene ions

Abstract

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