Cobalt-catalyzed biphasic hydroformylation of internal short chain olefins

Matthias Beller, Jürgen G.E. Krauter

Publikation: Beitrag in FachzeitschriftArtikelBegutachtung

66 Zitate (Scopus)

Abstract

Hydroformylation of short chain internal olefins to linear aldehydes is an interesting subject due to the enormous importance of the resulting oxo products. Here we report a systematic study of the hydroformylation of 2- pentenes in an aqueous two-phase system with a Co/TPPTS catalyst. At elevated temperatures and pressures good yields of the desired aldehydes were obtained. Linear to branched ratios (n/iso) of up to 70:30 were observed. Recycling of the catalyst and reuse up to four times without loss of activity has been demonstrated.

OriginalspracheEnglisch
Seiten (von - bis)31-39
Seitenumfang9
FachzeitschriftJournal of Molecular Catalysis A: Chemical
Jahrgang143
Ausgabenummer1-3
DOIs
PublikationsstatusVeröffentlicht - 8 Juli 1999
Extern publiziertJa

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