An improved ruthenium catalyst for the environmentally benign amination of primary and secondary alcohols

Dirk Hollmann, Annegret Tillack, Dirk Michalik, Ralf Jackstell, Matthias Beller

Publikation: Beitrag in FachzeitschriftArtikelBegutachtung

202 Zitate (Scopus)

Abstract

The N-alkylation of amines in the presence of different ruthenium catalysts generated in situ was investigated. Among the various catalysts tested, the combination of [Ru3(CO)12] and N-phenyl-2- (dicyclohexylphosphanyl)pyrrole showed the best performance. By applying this novel catalyst, a variety of functionalized alcohols and amines were converted into the corresponding secondary amines in high yield.

OriginalspracheEnglisch
Seiten (von - bis)403-410
Seitenumfang8
FachzeitschriftChemistry - An Asian Journal
Jahrgang2
Ausgabenummer3
DOIs
PublikationsstatusVeröffentlicht - 2007
Extern publiziertJa

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