AlCp* as a directing ligand: C-H and Si-H bond activation at the reactive intermediate [Ni(AlCp*)3]

Tobias Steinke; Christian Gemel; Mirza Cokoja; Manuela Winter; Roland A. Fischer

doi:10.1002/anie.200353114

AlCp* as a directing ligand: C-H and Si-H bond activation at the reactive intermediate [Ni(AlCp*)₃]

Tobias Steinke, Christian Gemel, Mirza Cokoja, Manuela Winter, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

103 Zitate (Scopus)

Abstract

As exotic as the title complexes are, and as classic as the concept of generating reactive, unsaturated intermediates [M (ER)_n] is (M = d block metal; E = Al, Ga, In; R = Cp*, C(SiMe₃)₃), there are still many surprises to come. Some of these are shown in the unexpected reactions of [Ni(AlCp*)₃] (see scheme; Cp* = C₅Me₅).

Originalsprache	Englisch
Seiten (von - bis)	2299-2302
Seitenumfang	4
Fachzeitschrift	Angewandte Chemie International Edition in English
Jahrgang	43
Ausgabenummer	17
DOIs	https://doi.org/10.1002/anie.200353114
Publikationsstatus	Veröffentlicht - 19 Apr. 2004
Extern publiziert	Ja

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10.1002/anie.200353114

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abstract = "As exotic as the title complexes are, and as classic as the concept of generating reactive, unsaturated intermediates [M (ER)n] is (M = d block metal; E = Al, Ga, In; R = Cp*, C(SiMe3)3), there are still many surprises to come. Some of these are shown in the unexpected reactions of [Ni(AlCp*)3] (see scheme; Cp* = C5Me5).",

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AU - Gemel, Christian

AU - Cokoja, Mirza

AU - Winter, Manuela

AU - Fischer, Roland A.

PY - 2004/4/19

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N2 - As exotic as the title complexes are, and as classic as the concept of generating reactive, unsaturated intermediates [M (ER)n] is (M = d block metal; E = Al, Ga, In; R = Cp*, C(SiMe3)3), there are still many surprises to come. Some of these are shown in the unexpected reactions of [Ni(AlCp*)3] (see scheme; Cp* = C5Me5).

AB - As exotic as the title complexes are, and as classic as the concept of generating reactive, unsaturated intermediates [M (ER)n] is (M = d block metal; E = Al, Ga, In; R = Cp*, C(SiMe3)3), there are still many surprises to come. Some of these are shown in the unexpected reactions of [Ni(AlCp*)3] (see scheme; Cp* = C5Me5).

KW - Aluminum

KW - C-H activation

KW - Group 13 elements

KW - Nickel

KW - Si-H activation

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