Activation of 2-Cyclohexenone by BF₃ Coordination: Mechanistic Insights from Theory and Experiment

Keyphrases

• Lewis Acids 100%
• Mechanistic Insight 100%
• Cyclohexanone 100%
• Highly Accurate 33%
• Boron 33%
• Dynamic Study 33%
• High Enantioselectivity 33%
• Transient Absorption 33%
• Enantioselectivity 33%
• Theoretical Treatment 33%
• CASPT2 33%
• Trajectory Calculation 33%
• Triplet State 33%
• Ultrafast Decay 33%
• Nonadiabatic Coupling 33%
• Decay Pathways 33%
• Photochemical Transformation 33%
• Photocycloaddition Reactions 33%
• Boron Trifluoride 33%
• Boron Analysis 33%
• Mechanistic Studies 33%
• Dynamic Base 33%
• Intersystem Crossing 33%

Chemistry

• Lewis Acid 100%
• Cyclohexenone 100%
• Enantioselectivity 33%
• Mechanistic Study 33%
• Intersystem Crossing [Singlet->triplet] 33%
• Triplet State 33%
• Boron Fluoride 33%