A novel As42+ structural unit with diphosphinomethanide bridging ligands from the reaction of AsCl3 with Li[C(PMe2)2(SiMe3)]

Hans H. Karsch; Annette Schier

doi:10.1039/C39940002703

A novel As₄²⁺ structural unit with diphosphinomethanide bridging ligands from the reaction of AsCl₃ with Li[C(PMe₂)₂(SiMe₃)]

Hans H. Karsch, Annette Schier

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Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

7 Zitate (Scopus)

Abstract

Two As₂[C(PMe₂)₂(SiMe₃)] five membered ring units are linked via an As-As bond and thus form an As ₄²⁺ chain in a compound obtained from a redox reaction between AsCl₃ and Li[C(PMe₂)₂(SiMe ₃)].

Originalsprache	Englisch
Seiten (von - bis)	2703-2704
Seitenumfang	2
Fachzeitschrift	Journal of the Chemical Society, Chemical Communications
Ausgabenummer	23
DOIs	https://doi.org/10.1039/C39940002703
Publikationsstatus	Veröffentlicht - 1994

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title = "A novel As42+ structural unit with diphosphinomethanide bridging ligands from the reaction of AsCl3 with Li[C(PMe2)2(SiMe3)]",

abstract = "Two As2[C(PMe2)2(SiMe3)] five membered ring units are linked via an As-As bond and thus form an As 42+ chain in a compound obtained from a redox reaction between AsCl3 and Li[C(PMe2)2(SiMe 3)].",

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AB - Two As2[C(PMe2)2(SiMe3)] five membered ring units are linked via an As-As bond and thus form an As 42+ chain in a compound obtained from a redox reaction between AsCl3 and Li[C(PMe2)2(SiMe 3)].

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M3 - Article

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

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