TY - JOUR
T1 - A new palladium(II) complex of a functionalized N-heterocyclic carbene
T2 - Synthesis, characterization and application in Suzuki-Miyaura cross-coupling reactions
AU - Linninger, Claudia S.
AU - Herdtweck, Eberhardt
AU - Hoffmann, Stephan D.
AU - Herrmann, Wolfgang A.
AU - Kühn, Fritz E.
PY - 2008/11/12
Y1 - 2008/11/12
N2 - trans-[PdBr2(NHC)Im] was prepared by reacting the corresponding imidazolium (Im) salt with palladium(II) acetate in dimethylsulfoxide in an in-situ reaction without generating a free carbene. Both the salt and the complex were characterized spectroscopically and by X-ray structure analysis. The complex was tested in homogeneous Suzuki-Miyaura cross-coupling reactions.
AB - trans-[PdBr2(NHC)Im] was prepared by reacting the corresponding imidazolium (Im) salt with palladium(II) acetate in dimethylsulfoxide in an in-situ reaction without generating a free carbene. Both the salt and the complex were characterized spectroscopically and by X-ray structure analysis. The complex was tested in homogeneous Suzuki-Miyaura cross-coupling reactions.
KW - Imidazolium salt
KW - N-heterocyclic carbene
KW - Palladium
KW - Suzuki-Miyaura cross-coupling
UR - http://www.scopus.com/inward/record.url?scp=53849115009&partnerID=8YFLogxK
U2 - 10.1016/j.molstruc.2008.05.037
DO - 10.1016/j.molstruc.2008.05.037
M3 - Article
AN - SCOPUS:53849115009
SN - 0022-2860
VL - 890
SP - 192
EP - 197
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
IS - 1-3
ER -