A neutral crystalline imino-substituted silyl radical

Fiona J. Kiefer; Arseni Kostenko; Richard Holzner; Shigeyoshi Inoue

doi:10.1039/d4cc02167c

A neutral crystalline imino-substituted silyl radical

Fiona J. Kiefer
, Arseni Kostenko
, Richard Holzner
, Shigeyoshi Inoue

Lehrstuhl für Siliciumchemie

Technische Universität München

Publikation: Beitrag in Fachzeitschrift › Artikel › Begutachtung

3 Zitate (Scopus)

Abstract

The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (I^tBuN-SiBr₃) with NaSi^tBu₂Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.

Originalsprache	Englisch
Seiten (von - bis)	8577-8580
Seitenumfang	4
Fachzeitschrift	Chemical Communications
Jahrgang	60
Ausgabenummer	65
DOIs	https://doi.org/10.1039/d4cc02167c
Publikationsstatus	Veröffentlicht - 10 Juli 2024

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10.1039/d4cc02167c

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title = "A neutral crystalline imino-substituted silyl radical",

abstract = "The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.",

author = "Kiefer, \{Fiona J.\} and Arseni Kostenko and Richard Holzner and Shigeyoshi Inoue",

note = "Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry.",

year = "2024",

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day = "10",

doi = "10.1039/d4cc02167c",

language = "English",

volume = "60",

pages = "8577--8580",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - A neutral crystalline imino-substituted silyl radical

AU - Kiefer, Fiona J.

AU - Kostenko, Arseni

AU - Holzner, Richard

AU - Inoue, Shigeyoshi

PY - 2024/7/10

Y1 - 2024/7/10

N2 - The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.

AB - The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.

UR - https://www.scopus.com/pages/publications/85199534306

U2 - 10.1039/d4cc02167c

DO - 10.1039/d4cc02167c

M3 - Article

C2 - 39045633

AN - SCOPUS:85199534306

SN - 1359-7345

VL - 60

SP - 8577

EP - 8580

JO - Chemical Communications

JF - Chemical Communications

IS - 65

ER -

A neutral crystalline imino-substituted silyl radical

Abstract

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